692778
(R,R)-DACH-naphthyl Trost ligand
95%
Synonym(s):
(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N′-bis(2-diphenylphosphino-1-naphthoyl)
About This Item
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Quality Level
Assay
95%
form
powder
optical activity
[α]20/D +69.0°, c = 1 in methanol
mp
224-231 °C
functional group
amide
phosphine
SMILES string
O=C(N[C@@H]1CCCC[C@H]1NC(=O)c2c(ccc3ccccc23)P(c4ccccc4)c5ccccc5)c6c(ccc7ccccc67)P(c8ccccc8)c9ccccc9
InChI
1S/C52H44N2O2P2/c55-51(49-43-29-15-13-19-37(43)33-35-47(49)57(39-21-5-1-6-22-39)40-23-7-2-8-24-40)53-45-31-17-18-32-46(45)54-52(56)50-44-30-16-14-20-38(44)34-36-48(50)58(41-25-9-3-10-26-41)42-27-11-4-12-28-42/h1-16,19-30,33-36,45-46H,17-18,31-32H2,(H,53,55)(H,54,56)/t45-,46-/m1/s1
InChI key
VXFKMKXTPXVEMU-AWSIMMLFSA-N
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Trost Ligands
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