333557
(1-Bromovinyl)trimethylsilane
97%
Synonym(s):
α-(Trimethylsilyl)vinyl bromide
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About This Item
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vapor density
>1 (vs air)
Quality Level
Assay
97%
form
liquid
refractive index
n20/D 1.458 (lit.)
bp
124 °C/745 mmHg (lit.)
density
1.156 g/mL at 25 °C (lit.)
functional group
bromo
storage temp.
2-8°C
SMILES string
C[Si](C)(C)C(Br)=C
InChI
1S/C5H11BrSi/c1-5(6)7(2,3)4/h1H2,2-4H3
InChI key
VVDJVCJVVHHCIB-UHFFFAOYSA-N
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General description
Tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reactions of (1-bromovinyl)trimethylsilane with organozinc bromides were studied.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Liq. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
55.4 °F - closed cup
Flash Point(C)
13 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Abnormal products of palladium catalysed coupling reactions of (1-bromovinyl) trimethylsilane.
Tetrahedron Letters, 30(28), 3735-3736 (1989)
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