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Key Documents

251127

Sigma-Aldrich

Bis(tributyltin)

95%

Synonym(s):

Hexabutyldistannane, Hexabutylditin

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About This Item

Linear Formula:
(CH3CH2CH2CH2)3SnSn(CH2CH2CH2CH3)3
CAS Number:
Molecular Weight:
580.11
Beilstein:
3605476
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

95%

form

liquid

refractive index

n20/D 1.512 (lit.)

density

1.148 g/mL at 25 °C (lit.)

SMILES string

CCCC[Sn](CCCC)(CCCC)[Sn](CCCC)(CCCC)CCCC

InChI

1S/6C4H9.2Sn/c6*1-3-4-2;;/h6*1,3-4H2,2H3;;

InChI key

REDSKZBUUUQMSK-UHFFFAOYSA-N

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General description

Bis(tributyltin) is utilized in tin-carbon bond formation, desulfurization, and deoxygenation reactions.

Application

Reagent used to stannylate aryl halides for subsequent Stille coupling. Also used in the radioiodination of styrlpyridines.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

266.0 °F - closed cup

Flash Point(C)

130 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Reagents for C–C Bond Formation

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