235067
Chlorotriethylsilane
99%
Synonym(s):
TESCl, Triethylchlorosilane
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About This Item
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Assay
99%
form
liquid
refractive index
n20/D 1.43 (lit.)
bp
142-144 °C (lit.)
density
0.898 g/mL at 25 °C (lit.)
SMILES string
CC[Si](Cl)(CC)CC
InChI
1S/C6H15ClSi/c1-4-8(7,5-2)6-3/h4-6H2,1-3H3
InChI key
DCFKHNIGBAHNSS-UHFFFAOYSA-N
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Application
Employed together with Grignard reagents in a palladium-catalyzed carbosilylation of allenes. The Grignard attacks the allene central carbon and the terminal carbon is silylated.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point(F)
86.0 °F
Flash Point(C)
30 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Journal of Organometallic Chemistry, 692, 375-375 (2007)
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