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D5004

Sigma-Aldrich

N,N-Dimethyl-p-phenylenediamine monohydrochloride

Synonym(s):

4-(Dimethylamino)aniline monohydrochloride, 4-Amino-N,N-dimethylaniline monohydrochloride, DMPPDA

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About This Item

Linear Formula:
(CH3)2NC6H4NH2·HCl
CAS Number:
2052-46-2
Molecular Weight:
172.66
Beilstein:
4546912
EC Number:
218-146-0
MDL number:
MFCD00012990
UNSPSC Code:
12352200
PubChem Substance ID:
24893912
NACRES:
NA.25

form

powder

mp

215 °C (dec.) (lit.)

storage temp.

−20°C

SMILES string

Cl[H].CN(C)c1ccc(N)cc1

InChI

1S/C8H12N2.ClH/c1-10(2)8-5-3-7(9)4-6-8;/h3-6H,9H2,1-2H3;1H

InChI key

KTWNIUBGGFBRKH-UHFFFAOYSA-N

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Caution

Darkens readily to grey powder when exposed to air.

Pictograms

Skull and crossbonesHealth hazard
GHS06,GHS08

Signal Word

Danger

Hazard Statements

H300,H311 + H331,H334

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Resp. Sens. 1

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SLBQ9683V
SLBL4139V
SLBF8835V
SLBC4206V
011M1482V

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Kraiwan Punyain et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 83(1), 368-378 (2011-09-20)
Organic radical cations form dicationic dimers in solution, observed experimentally as diamagnetic species in temperature-dependent EPR and low temperature UV/Vis spectroscopy. Dimerization of paraphenylenediamine, N,N-dimethyl-paraphenylenediamine and 2,3,5,6-tetramethyl-paraphenylenediamine radical cation in ethanol/diethylether mixture was investigated theoretically according to geometry, energetics and
F Tessier et al.
International journal for vitamin and nutrition research. Internationale Zeitschrift fur Vitamin- und Ernahrungsforschung. Journal international de vitaminologie et de nutrition, 66(2), 166-170 (1996-01-01)
An HPLC micro-method with fluorescence detection has been developed to determine total vitamin C (vit C) and dehydroascorbic acid (DHA) concentrations in human plasma samples. This method is based on the rapid, specific reaction of DHA with dimethyl-o-phenylenediamine (DMPD) to
Joseph B Issa et al.
The journal of physical chemistry. B, 111(24), 6878-6886 (2007-06-02)
Photoinduced intramolecular charge separation across proline-bridged donor-acceptor complexes of the type Pyr-(Pro)n-DMPD (where Pyr=pyrene-1-sulfonyl and DMPD=N,N-dimethyl-1,4-phenylenediamine) was studied. The steady-state emission spectrum for n=0, 1, 2, 3 showed an increase in emission intensity with the number of proline residues. Time-dependent
K Wimalasena et al.
The Journal of biological chemistry, 271(42), 26032-26043 (1996-10-18)
The interactions of reductants with dopamine beta-monooxygenase (DbetaM) were examined using two novel classes of reductants. The steady-state kinetics of the previously characterized DbetaM reductant, N,N-dimethyl-1,4-p-phenylenediamine (DMPD), were parallel to the ascorbic acid-supported reaction with respect to pH dependence and
Veronica Verde et al.
Free radical research, 36(8), 869-873 (2002-11-08)
Oxidative stress has been clearly implicated in human disease by a growing body of scientific evidences. There is no ideal method for the measurement of this parameter. A possible strategy would be to measure simultaneously several biomarkers representing damage to
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