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MilliporeSigma

P5958

Sigma-Aldrich

Hidróxido de potasio

BioXtra, ≥85% KOH basis

Sinónimos:

Potasa cáustica

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About This Item

Fórmula lineal:
KOH
Número de CAS:
Peso molecular:
56.11
EC Number:
MDL number:
UNSPSC Code:
12352106
eCl@ss:
38100303
PubChem Substance ID:
NACRES:
NA.21

vapor pressure

1 mmHg ( 719 °C)

Quality Level

product line

BioXtra

assay

≥85% KOH basis

form

pellets

impurities

≤0.0005% Phosphorus (P)
≤0.1% Insoluble matter
≤2.0% K2CO3

pH

~13.5 (25 °C, 5.6 g/L)

mp

361 °C (lit.)

solubility

H2O: 1 M, clear, colorless

anion traces

chloride (Cl-): ≤0.01%
sulfate (SO42-): ≤0.003%

cation traces

Al: ≤0.0005%
Ca: ≤0.0005%
Cu: ≤0.0005%
Fe: ≤0.0005%
Mg: ≤0.0005%
NH4+: ≤0.05%
Na: ≤0.05%
Pb: ≤0.001%
Zn: ≤0.0005%

SMILES string

[OH-].[K+]

InChI

1S/K.H2O/h;1H2/q+1;/p-1

InChI key

KWYUFKZDYYNOTN-UHFFFAOYSA-M

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General description

Potassium hydroxide is an inorganic compound commonly known as caustic potash. It is a strong alkali, readily reacts with acids. It can be used in various reactions such as nucleophilic substitution, hydrolysis, and addition reactions. Sometimes it can also be used as a catalyst for aldol-type reactions.

Application

Potassium hydroxide can be used to adjust the pH of the solution.
It can also be used:
  • As a catalyst in the alkynylation of heteroaromatic N-oxides to synthesize corresponding C2-alkynylheterocycles.
  • As a superbase medium with dimethyl sulfoxide (KOH/DMSO medium) for the synthesis of cross-coupling products under transition metal-free conditions from reactions between aryl halides and various sulfur, oxygen and nitrogen-based nucleophiles.
  • In the synthesis and thermodynamic study of Na-based zeolites.

pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


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Iulia I Nita et al.
PloS one, 7(10), e46649-e46649 (2012-10-12)
Mitochondria mediate dual metabolic and Ca(2+) shuttling activities. While the former is required for Ca(2+) signalling linked to insulin secretion, the role of the latter in β cell function has not been well understood, primarily because the molecular identity of
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Jae Myoung Suh et al.
Nature, 513(7518), 436-439 (2014-07-22)
Fibroblast growth factor 1 (FGF1) is an autocrine/paracrine regulator whose binding to heparan sulphate proteoglycans effectively precludes its circulation. Although FGF1 is known as a mitogenic factor, FGF1 knockout mice develop insulin resistance when stressed by a high-fat diet, suggesting a
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Bioresource technology, 130, 696-702 (2013-01-22)
In this work, preparation of granular activated carbon from oil palm biodiesel solid residue, oil palm shell (PSAC) by microwave assisted KOH activation has been attempted. The physical and chemical properties of PSAC were characterized using scanning electron microscopy, volumetric

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