208221

Iodine monochloride

reagent grade, ≥95%

• Sinónimos: Chloroiodide
• Fórmula lineal: ICl
• Número de CAS: 7790-99-0
• Peso molecular: 162.36
• EC Number: 232-236-7
• MDL number: MFCD00011354
• UNSPSC Code: 12352300
• PubChem Substance ID: 329752040
• NACRES: NA.21

Propiedades

• grade: reagent grade
• Quality Level: 200
• assay: ≥95%
• form: solid or liquid
• bp: 97.4 °C (lit.)
• density: 3.24 g/mL at 25 °C (lit.)
• storage temp.: 2-8°C
• SMILES string: ClI
• InChI: 1S/ClI/c1-2
• InChI key: QZRGKCOWNLSUDK-UHFFFAOYSA-N

Descripción

General description

Iodine monochloride is an interhalogen compound. It forms various complexes with ethyl, isopropyl and t-butylbenzenes. Electrically conducting solution of ICl is obtained on dissolution of ICl in polar solvents. ICl is a green oxidizing agent and participates in the following transformations:

• aldose hemiacetals to the corresponding aldose lactones
• diarylmethanols to the corresponding diarylmethanones
• arylalkylmethanols to the corresponding arylalkylmethanones
• dialkylmethanols to the corresponding dialkylmethanones

Application

Iodine monochloride (ICl) may be employed as a reagent in the following processes:

• Halogenation of methoxy and dimethoxybenzenes
• Synthesis of flavones.
• Preparation of 1-naphthaldehydes.

It may be used as an iodinating agent in the conversion of alkylboranes to alkyl iodides.

Información de seguridad

• pictograms: GHS05,GHS07
• signalword: Danger
• hcodes: H314,H335
• pcodes: P261 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 8B - Non-combustible corrosive hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable