ALD00412

Ethyl 4-(fluorosulfonyloxy)benzoate

• Fórmula empírica (notación de Hill): C₉H₉FO₅S
• Peso molecular: 248.23
• UNSPSC Code: 12352100
• PubChem Substance ID: 329772669
• NACRES: NA.22

Propiedades

• description: Fp: >230°F
• Quality Level: 100
• form: liquid
• refractive index: n20/D 1.479
• density: 1.340 g/mL at 25 °C
• SMILES string: O=S(OC1=CC=C(C(OCC)=O)C=C1)(F)=O
• InChI: 1S/C9H9FO5S/c1-2-14-9(11)7-3-5-8(6-4-7)15-16(10,12)13/h3-6H,2H2,1H3
• InChI key: WSJHOCQDJHFOCL-UHFFFAOYSA-N

Descripción

Application

The following aryl fluorosulfate can be utilized as a cross-coupling partner in Suzuki-Miyaura reactions. The standard reaction conditions for these palladium-catalyzed C-C bond formations are ligand-free and can be performed in water, at room temperatre and are not air sensitive.

Other Notes

Palladium-Catalyzed, Ligand-Free Suzuki Reaction in Water Using Aryl Fluorosulfates

Información de seguridad

• pictograms: GHS05
• signalword: Danger
• hcodes: H314
• pcodes: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Skin Corr. 1B
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable