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MilliporeSigma

906921

Sigma-Aldrich

PQT-12

Sinónimos:

Poly(3,3′′′-didodecyl[2,2′:5′,2′′:5′′,2′′′-quaterthiophene]-5,5′′′-diyl), Poly(4,4′′-didodecyl[2,2′:5′,2′′:5′′,2′′′-quaterthiophene]-5,5′′′-diyl)

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About This Item

Fórmula lineal:
(C40H56S4)n
Número de CAS:
UNSPSC Code:
12162002
NACRES:
NA.23

description

Band gap: 2.27 eV
Eox = 0.45 V
Solution processable (chloroform, chlorobenzene, etc)
LIFT transferable

form

solid

mol wt

Mw 10,000-25,000 by GPC

color

brown

solubility

>5 mg/mL (in CHCl3)

λmax

473 nm in toluene

orbital energy

HOMO -5.24 eV 
LUMO -2.97 eV 

storage temp.

15-25°C

Application

PQT-12 can be employed as the semiconductor material in organic field-effect transistors(OFETs). Its high charge carrier mobility, good film-forming properties, and stability make it useful for the channel layer, enabling efficient electronic device performance. The conjugated polymer structure and charge storage capability of PQT-12 make it potentially useful for energy storage applications such as super capacitors and batteries.
PQT-12 exhibits strong absorption in the visible and near-infrared regions of the spectrum. This property enables effective utilization of a broad range of solar radiation, enhancing the light-harvesting capability and efficiency of OPV devices. PQT-12 can serve as the donor material in the active layer of OPV devices. PQT-12′s unique properties and charge transport characteristics contribute to the development of low voltage and low-power OFET devices. Its high charge carrier mobility allows for better device performance with lower operational voltages.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Visite la Librería de documentos

Highly flexible chemical sensors based on polymer nanofiber field-?effect transistors
Kweon O Y, et al
Journal of Material Chemistry C (2019)
Modification of the Poly(bisdodecylquaterthiophene) Structure for High and Predominantly Nonionic Conductivity with Matched Dopants
Hui Li, et al.
Journal of the American Chemical Society, 139,, 11149- 11157 (2017)
Highly Flexible Organic Nanofiber Phototransistors Fabricated on a Textile Composite for Wearable Photosensors
Lee M Y, et al.
Advances in Functional Materials, (2016), 1445-1445 (2016)
Laser printed organic semiconductor PQT-12 for bottom-gate organic thin-film transistors: Fabrication and characterization
Makrygianni M, et al.
Journal of Chemical and Pharmaceutical Sciences, 390, 823-830 (2016)
Self-assembly of regioregular poly (3,3'''-didodecylquarterthiophene) in chloroform and study of its junction properties
Singh M K, et al.
Journal of Chemical and Pharmaceutical Sciences , 217, 12-17 (2017)

Artículos

Professor Tokito and Professor Takeda share their new materials, device architecture design principles, and performance optimization protocols for printed and solution-processed, low-cost, highly flexible, organic electronic devices.

Professor Chen (Nankai University, China) and his team explain the strategies behind their recent record-breaking organic solar cells, reaching a power conversion efficiency of 17.3%.

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