752150

Ethyl diazoacetate solution

15% in toluene

• Sinónimos: 2-Diazoacetic acid ethyl ester solution
• Fórmula empírica (notación de Hill): C₄H₆N₂O₂
• Número de CAS: 623-73-4
• Peso molecular: 114.10
• MDL number: MFCD00001989
• UNSPSC Code: 12352100
• PubChem Substance ID: 329766264
• NACRES: NA.22

Propiedades

• form: liquid
• concentration: 15% in toluene
• refractive index: n20/D 1.505
• density: 0.895 g/mL at 25 °C
• functional group: ester
• storage temp.: 2-8°C
• SMILES string: CCOC(=O)C=[N+]=[N-]
• InChI: 1S/C4H6N2O2/c1-2-8-4(7)3-6-5/h3H,2H2,1H3
• InChI key: YVPJCJLMRRTDMQ-UHFFFAOYSA-N

Descripción

General description

Ethyl diazoacetate solution is a diazo compound that is used as a reagent for the cyclopropanation of unsaturated compounds. It is used to prepare cyclopropane and cyclopropane carboxylic acid derivatives by catalytic decomposition of ethyl diazoacetate in the presence of alkenes. It is also a useful reagent for the homologation of cyclic and acyclic ketones without the formation of epoxides as byproducts.

Application

New Diazoacetate Formulations

Información de seguridad

• pictograms: GHS02,GHS08,GHS07
• signalword: Danger
• hcodes: H225,H304,H315,H336,H351,H361d,H373,H412
• pcodes: P202 - P210 - P273 - P301 + P310 - P303 + P361 + P353 - P331
• Hazard Classifications: Aquatic Chronic 3 - Asp. Tox. 1 - Carc. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
• target_organs: Central nervous system
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 39.9 °F - closed cup
• flash_point_c: 4.4 °C - closed cup