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692921

Bis[di-(tert-butyl)(4-trifluoromethylphenyl)phosphine]palladium(II) chloride

Name: Bis[di-(<I>tert</I>-butyl)(4-trifluoromethylphenyl)phosphine]palladium(II) chloride
Brand: ALDRICH

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About This Item

Fórmula empírica (notación de Hill):

C₃₀H₄₄Cl₂F₆P₂Pd

Número de CAS:

887919-36-0

Peso molecular:

757.93

MDL number:

MFCD11045389

UNSPSC Code:

12352300

PubChem Substance ID:

329761542

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Slide 1 of 1

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Sigma-Aldrich

638064

XPhos

form

powder

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

mp

230 °C (D)

functional group

phosphine

SMILES string

Cl[Pd]Cl.CC(C)(C)P(c1ccc(cc1)C(F)(F)F)C(C)(C)C.CC(C)(C)P(c2ccc(cc2)C(F)(F)F)C(C)(C)C

InChI

1S/2C15H22F3P.2ClH.Pd/c2*1-13(2,3)19(14(4,5)6)12-9-7-11(8-10-12)15(16,17)18;;;/h2*7-10H,1-6H3;2*1H;/q;;;;+2/p-2

InChI key

ATVRGWRBZLLSJD-UHFFFAOYSA-L

Application

Catalyst for Suzuki Coupling reaction of heteroaryl chlorides

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificados de análisis (COA)

Lot/Batch Number

09215AJ

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New catalysts for Suzuki-Miyaura coupling reactions of heteroatom-substituted heteroaryl chlorides.

Anil S Guram et al.

The Journal of organic chemistry, 72(14), 5104-5112 (2007-06-07)

The new air-stable PdCl2[PR2(Ph-R')]2 complexes, readily prepared from commercial reagents, exhibit unique efficiency as catalysts for the Suzuki-Miyaura coupling reactions of a variety of heteroatom-substituted heteroaryl chlorides with a diverse range of aryl/heteroaryl boronic acids. The coupling reactions catalyzed by

New air-stable catalysts for general and efficient suzuki-miyaura cross-coupling reactions of heteroaryl chlorides.

Anil S Guram et al.

Organic letters, 8(9), 1787-1789 (2006-04-21)

[reaction: see text] New air-stable PdCl(2){P(t)Bu(2)(p-R-Ph)}(2) (R = H, NMe(2), CF(3),) complexes represent simple, general, and efficient catalysts for the Suzuki-Miyaura cross-coupling reactions of aryl halides including five-membered heteroaryl halides and heteroatom-substituted six-membered heteroaryl chlorides with a diverse range of

Artículos

An Introduction to A-Phos, its Applications and Advantages

Ligand used to prepare a palladium dichloride catalyst on treatment with PdCl2(COD). The catalyst effectively cross-couples aryl boronic acids with heteroaryl chlorides.

A-Phos

A-Phos Palladium Complexes for Efficient Suzuki Coupling

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