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MilliporeSigma

471364

Sigma-Aldrich

1-Dodecanethiol

≥98%

Sinónimos:

n-Dodecyl mercaptan, Dodecyl mercaptan, Lauryl mercaptan, Mercaptan C12, NDM

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About This Item

Fórmula lineal:
CH3(CH2)11SH
Número de CAS:
Peso molecular:
202.40
Beilstein/REAXYS Number:
969337
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

vapor density

7 (vs air)

Quality Level

assay

≥98%

refractive index

n20/D 1.459 (lit.)

bp

266-283 °C (lit.)

density

0.845 g/mL at 25 °C (lit.)

SMILES string

CCCCCCCCCCCCS

InChI

1S/C12H26S/c1-2-3-4-5-6-7-8-9-10-11-12-13/h13H,2-12H2,1H3

InChI key

WNAHIZMDSQCWRP-UHFFFAOYSA-N

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General description

1-Dodecanethiol (DDT) is an alkyl thiol that forms a self-assembled monolayer (SAM) and can be used as an organic source of sulfur with balanced physio-chemical properties.

Application

DDT can be used as a source of sulfur for the synthesis CdS quantum dots (QDs) and lead sulfide nanoparticles (PbS) which find potential applications in energy efficient lighting, solar cells and as ammonium gas sensing agents. It may be used to form a self-assembled monolayer (SAM) on copper surface as a corrosion resistant coating. Functionalization with DDT may form SAMs on geranium (Ge) to improve the surface characteristics for futuristic applications in microelectronics.
This molecule is used for the production of hydrophobic SAMs. It can also be used in mixed SAMs to give a hydrophobic background and act as a spacer to move other functional groups or domains farther apart.

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1C - Skin Sens. 1A

Storage Class

8A - Combustible, corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

262.4 °F - closed cup

flash_point_c

128 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Certificados de análisis (COA)

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Visite la Librería de documentos

Chemical synthesis and optical characterization of regular and magic-sized CdS quantum dot nanocrystals using 1-dodecanethiol.
Dickson R and Hu M
Journal of Materials Research, 30(7), 890-895 (2015)
Inhibition Effect of 3D Nanostructures on the Corrosion Resistance of 1-Dodecanethiol Self-Assembled Monolayers on Copper in Nacl Solution.
Shuai Hm et al.
Materials, 8(10), 11661-11679 (2018)
Functions of 1-Dodecanethiol in the Synthesis and Post-treatment of Copper Sulfide Nanoparticles Relevant to Their Photocatalytic Applications.
Lihui C and Guohua L
ACS Applied Nano Materials, 1(9), 4587?4593-4587?4593 (2018)
Pham Hong Phong et al.
Langmuir : the ACS journal of surfaces and colloids, 21(23), 10581-10586 (2005-11-03)
Ternary self-assembled monolayers (SAM) composed of 2-aminoethanethiol (AET), 2-mercaptoethanesulfonic acid (MES), and 1-dodecanethiol (DDeT) form two types of domains as if it were a two-component SAM: DDeT-rich hydrophobic domains and electrostatically stabilized hydrophilic domains composed of MES and AET on
Synthesis and characterization of PbS nanoparticles in an ionic liquid using single and dual source precursors.
Tshemese Z, et al.
Materials Science and Engineering, B, 227(7), 116-121 (2018)

Artículos

To keep pace with Moore′s Law, there is a continuing need in the semiconductor industry to achieve higher circuit density in microelectronic devices.

1-Adamantanethiol (1-AD), an example in this spectrum of molecules with distinct chemical and physical properties, forms self-assembled monolayers (SAMs) on Au{111} that are displaceable when exposed to other thiolated molecules from solution, vapor, or contact due to weak intermolecular interactions in 1-AD SAMs.

Single molecule electronics is the endeavour of constructing electronic circuitry with single molecules as the fundamental building block.

Solvothermal synthesis is a method for preparing a variety of materials such as metals, semiconductors, ceramics, and polymers.

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