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357324

Iridium

Name: Iridium
Brand: ALDRICH

foil, thickness 0.25 mm, 99.9% trace metals basis

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About This Item

Fórmula empírica (notación de Hill):

Número de CAS:

7439-88-5

Peso molecular:

192.22

MDL number:

MFCD00011062

UNSPSC Code:

12141720

PubChem Substance ID:

24861904

NACRES:

NA.23

assay

99.9% trace metals basis

form

foil

resistivity

4.71 μΩ-cm

thickness

0.25 mm

bp

4130 °C (lit.)

mp

2450 °C (lit.)

density

22.65 g/cm³ (lit.)

SMILES string

[Ir]

InChI

1S/Ir

InChI key

GKOZUEZYRPOHIO-UHFFFAOYSA-N

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Quantity

3.5 g = 25 × 25 mm

Storage Class

13 - Non Combustible Solids

wgk_germany

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Sigma-Aldrich

267244

Platinum

Enantioselective iridium-catalyzed hydrogenation of 1- and 3-substituted isoquinolinium salts.

Zhi-Shi Ye et al.

Angewandte Chemie (International ed. in English), 52(13), 3685-3689 (2013-02-21)

A highly selective and non-reaction based chemosensor for the detection of Hg2+ ions using a luminescent iridium(III) complex.

Daniel Shiu-Hin Chan et al.

PloS one, 8(3), e60114-e60114 (2013-03-28)

We report herein a novel luminescent iridium(III) complex with two hydrophobic carbon chains as a non-reaction based chemosensor for the detection of Hg(2+) ions in aqueous solution (<0.002% of organic solvent attributed to the probe solution). Upon the addition of

Iridium-catalyzed C-H borylation of cyclopropanes.

Carl W Liskey et al.

Journal of the American Chemical Society, 135(9), 3375-3378 (2013-02-21)

The borylation of cyclopropanes catalyzed by the combination of (η(6)-mes)IrBpin3 or [Ir(COD)OMe]2 and a phenanthroline derivative is reported. The borylation occurs selectively at the methylene C-H bonds of the cyclopropane ring over methine or methyl C-H bonds. High diasteroselectivities were

Luminescent biscarbene iridium(III) complexes as living cell imaging reagents.

Yuyang Zhou et al.

Chemical communications (Cambridge, England), 49(31), 3230-3232 (2013-03-14)

Five iridium(III) complexes with two N-heterocyclic carbene (NHC) ligands and an ancillary ligand have been designed and successfully synthesized. With multicolor photoluminescence and low toxicity, these carbene complexes were tested, for the first time, as living cell imaging reagents and

Ir(I)-catalyzed synthesis of N-substituted pyridones from 2-alkoxypyridines via C-O bond cleavage.

Shiguang Pan et al.

Organic letters, 15(8), 1902-1905 (2013-04-02)

A cationic Ir(I) complex-catalyzed O-to-N-alkyl migration in 2-alkoxypyridines bearing a secondary alkyl group on the oxygen atom by C-O bond cleavage is described. The present transformation gave various N-alkylpyridones in moderate to good yields. The addition of sodium acetate played

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