29524

(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine]

≥97%, optical purity ee: ≥99%

• Sinónimos: (R)-2,2′-Bis[bis(3,5-di-tert-butyl)phosphino]-6,6′-dimethoxy-1,1′-biphenyl, (R)-3,5-t-Bu-MeOBIPHEP, SL-A121-2
• Fórmula empírica (notación de Hill): C₇₀H₉₆O₂P₂
• Número de CAS: 192138-05-9
• Peso molecular: 1031.46
• MDL number: MFCD09753001
• UNSPSC Code: 12352112
• PubChem Substance ID: 329753371
• NACRES: NA.22

Propiedades

• Quality Level: 100
• assay: ≥97%
• optical purity: ee: ≥99%
• SMILES string: COc1cccc(P(c2cc(cc(c2)C(C)(C)C)C(C)(C)C)c3cc(cc(c3)C(C)(C)C)C(C)(C)C)c1-c4c(OC)cccc4P(c5cc(cc(c5)C(C)(C)C)C(C)(C)C)c6cc(cc(c6)C(C)(C)C)C(C)(C)C
• InChI: 1S/C70H96O2P2/c1-63(2,3)45-33-46(64(4,5)6)38-53(37-45)73(54-39-47(65(7,8)9)34-48(40-54)66(10,11)12)59-31-27-29-57(71-25)61(59)62-58(72-26)30-28-32-60(62)74(55-41-49(67(13,14)15)35-50(42-55)68(16,17)18)56-43-51(69(19,20)21)36-52(44-56)70(22,23)24/h27-44H,1-26H3
• InChI key: PBYRAYONARLAQJ-UHFFFAOYSA-N

Descripción

General description

sold in collaboration with Solvias AG

Application

Atropisomeric MeOBIPHEP ligands

(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] can be used as a ligand to prepare:

• 1,2-Dihydropyridines through Rh-catalyzed cycloaddition of diynes to sulfonimines.
• Enantiorich disubstituted γ-lactams via intramolecular allylic alkylation reaction using Pd catalyst.
• A Ru-metal complex, which acts as a hydrogenation catalyst applicable in the synthesis of an organic building block (S)-3-fluoromethyl-γ-butyrolactone.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Información de seguridad

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)