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288055

Sigma-Aldrich

Cyclopentadienylmanganese(I) tricarbonyl

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About This Item

Fórmula lineal:
C5H5Mn(CO)3
Número de CAS:
12079-65-1
Peso molecular:
204.06
EC Number:
235-142-4
MDL number:
MFCD00001440
UNSPSC Code:
12352103
PubChem Substance ID:
24857312
NACRES:
NA.23

Quality Level

100

form

powder or crystals

composition

Mn, 26.0-27.9% EDTA titration

reaction suitability

core: manganese
reagent type: catalyst

mp

72-76 °C (lit.)

SMILES string

[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1

InChI

1S/C5H5.3CO.Mn/c1-2-4-5-3-1;3*1-2;/h1-5H;;;;

InChI key

CZPHEHHRMHXAIK-UHFFFAOYSA-N

Categorías relacionadas

pictograms

Skull and crossbones
GHS06

signalword

Danger

hcodes

H300

Hazard Classifications

Acute Tox. 2 Oral

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificados de análisis (COA)

Lot/Batch Number
MKCF2541
MKCD8175
MKBZ0743V
MKBZ0742V
MKBX8112V

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Cobalt carbonyl moistened with hexane (hexane 1-10%), ≥90% (Co)

Sigma-Aldrich

60811

Cobalt carbonyl

Benzene-chromium(0) tricarbonyl 98%

Sigma-Aldrich

119318

Benzene-chromium(0) tricarbonyl

I Rémy et al.
Journal of pharmaceutical and biomedical analysis, 9(10-12), 965-967 (1991-01-01)
Biotin labelled with a cymantrene moiety (cyclopentadienyl manganese tricarbonyl complex) is described for the first time. Because this metallo-biotin retains full recognition for the specific glycoprotein avidin (or streptavidin), the labelled streptavidin-biotin system is proposed for use in a solid-phase
Katrin Splith et al.
Bioconjugate chemistry, 21(7), 1288-1296 (2010-07-01)
Over the past years, numerous promising new metalorganic lead structures have been developed exhibiting highly active cytostatic properties. However, the efficiency of such chemotherapeutics in the treatment of tumors is often limited by their low therapeutic index due to their
Ricardo Picciochi et al.
The journal of physical chemistry. A, 112(41), 10429-10434 (2008-09-20)
The standard molar enthalpy of sublimation of monoclinic cyclopentadienyltricarbonylmanganese, Mn(eta (5)-C 5H 5)(CO) 3, at 298.15 K, was determined as Delta sub H m (o)[Mn(eta (5)-C 5H 5)(CO) 3] = 75.97 +/- 0.37 kJ x mol (-1) from Knudsen effusion
J Zayed et al.
American Industrial Hygiene Association journal, 55(1), 53-58 (1994-01-01)
Occupational and environmental exposure to airborne manganese has been measured for two groups of workers in Montreal, taxi drivers and garage mechanics. In Canada methylcyclopentadienyl manganese tricarbonyl (MMT) has replaced lead as an anti-knock agent in gasoline and represents a
R J Clay et al.
Toxicology and applied pharmacology, 98(3), 434-443 (1989-05-01)
The acute pneumotoxic effects of cyclopentadienyl manganese tricarbonyl (CMT) and methylcyclopentadienyl manganese tricarbonyl (MMT) were compared to delineate the role of the methyl side chain in the toxicity of these organomanganese compounds and to further our understanding of the mechanisms
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