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104876

Sigma-Aldrich

Trichlorovinylsilane

97%

Sinónimos:

(Trichlorosilyl)ethylene, Vinyltrichlorosilane

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About This Item

Fórmula lineal:
H2C=CHSiCl3
Número de CAS:
75-94-5
Peso molecular:
161.49
Beilstein/REAXYS Number:
1743440
EC Number:
200-917-8
MDL number:
MFCD00000482
UNSPSC Code:
12162002
PubChem Substance ID:
24846680
NACRES:
NA.23

vapor density

>1 (vs air)

vapor pressure

60 mmHg ( 23 °C)

assay

97%

refractive index

n20/D 1.436 (lit.)

bp

90 °C (lit.)

mp

−95 °C (lit.)

density

1.27 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

Cl[Si](Cl)(Cl)C=C

InChI

1S/C2H3Cl3Si/c1-2-6(3,4)5/h2H,1H2

InChI key

GQIUQDDJKHLHTB-UHFFFAOYSA-N

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General description

Trichlorovinylsilane may react with lithium-tert-butyl, and 1,3-enynes to yield isomeric silacyclobutanes and silacyclobutenes respectively.

Application

A study reports the possible use of this silane for treating Pluronic F127, chitosan for better attachment and proliferation of endothelial cells on biomaterials. Trichlorovinylsilane may be used to prepare epoxy terminated carbosiloxane.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

50.0 °F - closed cup

flash_point_c

10 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificados de análisis (COA)

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John D DeSain et al.
Physical chemistry chemical physics : PCCP, 8(19), 2240-2248 (2006-05-12)
The absolute gas phase ultraviolet absorption spectra of trichlorovinylsilane and allyltrichlorosilane have been measured from 191 to 220 nm. Over this region the absorption spectra of both species are broad and relatively featureless, and their cross sections increase with decreasing
Trichlorovinylsilane, lithium-tert-butyl, and 1, 3-enynes: A versatile combination for the competitive formation of silacyclobutanes and silacyclobutenes.
Canadian Journal of Chemistry, 78(11), 1445-1458 (2000)
Xiangming Wu et al.
Colloids and surfaces. B, Biointerfaces, 130, 69-76 (2015-04-25)
Earlier work provided direction for development of responsive drug delivery systems based on modulation of the structure, amphiphilicity, and surface density of bioactive peptides entrapped within pendant polyethylene oxide (PEO) brush layers. In this work, we describe the sequential and
Synthesis, characterization of an epoxy?terminated carbosiloxane and its application as a modifier in epoxy systems.
Polym. Eng. Sci., 52(4), 868-874 (2012)
Yu Chi Wang et al.
FASEB journal : official publication of the Federation of American Societies for Experimental Biology, 18(3), 525-527 (2004-01-13)
Controlling the spatial organization of cells is vital in engineering tissues that require precisely defined cellular architectures. For example, functional nerves or blood vessels form only when groups of cells are organized and aligned in very specific geometries. Yet, scaffold
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