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Merck
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重要文件

CRM51838

Supelco

2,4,5-三氯苯氧基乙酸

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

同義詞:

2,4,5-T

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About This Item

線性公式:
Cl3C6H2OCH2CO2H
CAS號碼:
分子量::
255.48
MDL號碼:
分類程式碼代碼:
41116107
NACRES:
NA.24

等級

certified reference material
TraceCERT®

品質等級

產品線

TraceCERT®

儲存期限

limited shelf life, expiry date on the label

製造商/商標名

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

mp

154-158 °C (lit.)

形式

neat

儲存溫度

−20°C

SMILES 字串

OC(=O)COc1cc(Cl)c(Cl)cc1Cl

InChI

1S/C8H5Cl3O3/c9-4-1-6(11)7(2-5(4)10)14-3-8(12)13/h1-2H,3H2,(H,12,13)

InChI 密鑰

SMYMJHWAQXWPDB-UHFFFAOYSA-N

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一般說明

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com2,4,5-T is a synthetic auxin that belongs to the family of chlorinated acid herbicides, used to defoliate broad-leafed plants.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, 2,4,5-T is not approved for use in the European Union. But a default maximum residue limit (MRL) of 0.01 mg/kg is applicable for the presence of 2,4,5-T (taken as a sum of 2,4,5-T, its salts, and esters) in products of plant origin, in accordance with Regulation (EC) No. 2015/868.

應用

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The 2,4,5-T CRM may also find use in the following:

  • Development of a multi-residue method for the determination of 24 plant growth regulators in 50 grape samples using a modified QuEChERS method and liquid chromatography-tandem mass spectrometry (LC-MS/MS)
  • Development and validation of a method that included acidified QuEChERS extraction and LC-MS/MS determinationͰ based on fast switching between positive and negative electrospray ionization modes, to analyze 35 acid herbicides in food matrices
  • Application of a novel amino-modified covalent organic framework (NH2@COF) as a solid phase extraction (SPE) absorbent to extract carboxylic acid pesticides from environmental water samples
  • Determination of 12 phenoxy carboxylic acids in water samples by using a metal-organic framework (MIL-101) for dispersive solid phase extraction (DSPE) followed by ultra-high performance liquid chromatographic-tandem mass spectrometric (UHPLC-MS/MS) analysis
  • Analysis of 26 acid herbicides in 309 soil samples by dispersive solid-phase extraction and liquid chromatography-tandem mass spectrometry (LC-MS/MS)
  • Investigating the use of magnetic polyethyleneimine-modified reduced graphene oxide (Fe3O4@PEI-RGO) as an adsorbent for the magnetic solid-phase extraction and HPLC determination of polar acidic herbicides in rice samples

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Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

法律資訊

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

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象形圖

Skull and crossbonesEnvironment

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

Lot/Batch Number

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Chris Sack et al.
Journal of agricultural and food chemistry, 63(43), 9657-9665 (2015-10-17)
A method for the determination of 35 acid herbicides in food matrices was developed, validated, and implemented. It utilizes a modified QuEChERS extraction procedure coupled with quantitation by liquid chromatography tandem mass spectrometry (LC-MS/MS). The acid herbicides analyzed are all
Na Li et al.
Analytica chimica acta, 949, 23-34 (2016-11-24)
A novel magnetic polyethyleneimine modified reduced graphene oxide (Fe3O4@PEI-RGO) had been fabricated based on a self-assemble approach between positive charged magnetic polyethyleneimine (Fe3O4@PEI) and negative charged GO sheets via electrostatic interaction followed by chemical reduction of GO to RGO. The
Chieh-Han Pu et al.
Journal of food and drug analysis, 26(2), 637-648 (2018-03-24)
A multiresidue analytical method was developed for grapes for the following 24 plant growth regulators: 1-naphthylacetamide, 2,3,5-triiodobenzoic acid, 2,4,5-T, 2-naphthoxyacetic acid, 3-indolylacetic acid, 4-(3-indolyl)-butyric acid, 4-chlorophenoxyacetic acid, 4-nitrophenol, 6-benzylaminopurine, N6-isopentenyladenine, butralin, chlormequat chloride, chlorphonim-Cl, cloprop, forchlorfenuron, gibberellic acid 3, gibberellic acid

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