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Merck
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重要文件

B1403

Sigma-Aldrich

Boc-L-alaninal

≥98%

同義詞:

Boc-L-alanine aldehyde

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About This Item

經驗公式(希爾表示法):
C8H15NO3
CAS號碼:
分子量::
173.21
MDL號碼:
分類程式碼代碼:
12352209
PubChem物質ID:
NACRES:
NA.26

product name

Boc-L-alaninal, ≥98%

品質等級

化驗

≥98%

形狀

powder

顏色

white

應用

peptide synthesis

儲存溫度

−20°C

SMILES 字串

C[C@H](NC(=O)OC(C)(C)C)C=O

InChI

1S/C8H15NO3/c1-6(5-10)9-7(11)12-8(2,3)4/h5-6H,1-4H3,(H,9,11)/t6-/m0/s1

InChI 密鑰

OEQRZPWMXXJEKU-LURJTMIESA-N

基因資訊

human ... CTSK(1513)

應用

Boc-L-alaninal is used as a reagent for organic synthesis of C(26)-C(32) Oxazole Fragment of Calyculin C and other molecules.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


分析證明 (COA)

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Petri M. Pihko et al.
The Journal of organic chemistry, 63(1), 92-98 (2001-10-25)
The synthesis of the C(26)-C(32) oxazole fragment 4 and its C(32) epimer 20 of serine/threonine protein phosphatase PP1 and PP2A inhibitor calyculin C is presented. The syn methyl arrangement in 4 was established through cyclic stereocontrol. Several methods for oxidizing
Johann Chan et al.
The Journal of organic chemistry, 76(6), 1767-1774 (2011-02-09)
Two new, reliable syntheses of a pyrido[2,3-d]-pyrimidine inhibitor of the CXCR3 receptor are described. A nine-step synthesis of the CXCR3 inhibitor (1) from 2-aminonicotinic acid was demonstrated on a multikilogram scale and incorporates a classic resolution to deliver the enantioenriched
James A Marshall et al.
Organic letters, 7(8), 1593-1596 (2005-04-09)
[reaction: see text] Additions of chiral allenylzinc and indium reagents to N-Boc alaninal were examined as a possible route to a C20-C26 segment of superstolide A. Allenylzinc reagents, prepared in situ by palladiozincation of (R)- and (S)-5-pivalyloxy-3-butyn-2-ol mesylate, showed excellent

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