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Merck
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重要文件

M46837

Sigma-Aldrich

甲酸甲酯

reagent grade, 97%

同義詞:

蚁酸甲酯

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About This Item

線性公式:
HCO2CH3
CAS號碼:
分子量::
60.05
Beilstein:
1734623
EC號碼:
MDL號碼:
分類程式碼代碼:
12352108
PubChem物質ID:
NACRES:
NA.21
bp:
32-34 °C (lit.)

等級

reagent grade

品質等級

蒸汽密度

2.1 (vs air)

蒸汽壓力

32.81 psi ( 55 °C)
9.21 psi ( 20 °C)

化驗

97%

形狀

liquid

自燃溫度

842 °F

expl. lim.

23 %

雜質

≤3% methyl alcohol

折射率

n20/D 1.343 (lit.)

pH值

4.0-5.0 (20 °C, 200 g/L)

bp

32-34 °C (lit.)

mp

−100 °C (lit.)

密度

0.974 g/mL at 20 °C (lit.)

SMILES 字串

[H]C(=O)OC

InChI

1S/C2H4O2/c1-4-2-3/h2H,1H3

InChI 密鑰

TZIHFWKZFHZASV-UHFFFAOYSA-N

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應用

Methyl formate may be used to prepare formamides via amine formaylation.

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 1 - STOT SE 1 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

-2.2 °F - closed cup

閃點(°C)

-19 °C - closed cup


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Rotational isomerism in methyl formate and methyl acetate; a low-temperature matrix infrared study using thermal molecular beams.
Blom CE and Gunthard HH.
Chemical Physics Letters, 84(2), 267-271 (1981)
Lucia Lanfri et al.
The journal of physical chemistry. A, 123(29), 6130-6143 (2019-07-04)
Following photodissociation at 248 nm of gaseous methyl formate (HC(O)OCH3, 0.73 Torr) and Ar (0.14 Torr), temporally resolved vibration-rotational emission spectra of highly internally excited CO (ν ≤ 11, J ≤ 27) in the 1850-2250 cm-1 region were recorded with
Catalytic reaction of methyl formate with amines to formamides.
Deutsch J, et al.
Tetrahedron, 65(50), 10365-10369 (2009)
Marine S Da Silva et al.
Prostaglandins, leukotrienes, and essential fatty acids, 126, 64-71 (2017-10-17)
This study aimed to determine whether dairy macronutrients alter markers of inflammation and oxidative stress in endothelial cells. Human endothelial cells (HUVEC) were treated with ruminant trans fatty acids (rTFA), either trans-vaccenic acid (tVA) or trans-palmitoleic acid (tPA), whey protein
Methyl formate as a new building block in C1 chemistry.
Lee JS, et al.
Applied Catalysis, 57(1), 1-30 (1990)

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