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重要文件

259705

Sigma-Aldrich

甲酸甲酯

spectrophotometric grade, ≥98%

同義詞:

蚁酸甲酯

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About This Item

線性公式:
HCO2CH3
CAS號碼:
分子量::
60.05
Beilstein:
1734623
EC號碼:
MDL號碼:
分類程式碼代碼:
12352108
PubChem物質ID:
NACRES:
NA.21
等級:
spectrophotometric grade
化驗:
≥98%
技術:
UV/Vis spectroscopy: suitable
bp:
32-34 °C (lit.)
蒸汽壓力:
32.81 psi ( 55 °C)
9.21 psi ( 20 °C)

等級

spectrophotometric grade

品質等級

蒸汽密度

2.1 (vs air)

蒸汽壓力

32.81 psi ( 55 °C)
9.21 psi ( 20 °C)

化驗

≥98%

形狀

liquid

自燃溫度

842 °F

expl. lim.

23 %

技術

UV/Vis spectroscopy: suitable

雜質

<0.010% water

蒸發殘留物

<0.0005%

折射率

n20/D 1.343 (lit.)

pH值

4.0-5.0 (20 °C, 200 g/L)

bp

32-34 °C (lit.)

mp

−100 °C (lit.)

密度

0.974 g/mL at 20 °C (lit.)

&lambda ;

H2O reference

紫外吸收

λ: 259 nm Amax: 1.00
λ: 260 nm Amax: 0.70
λ: 265 nm Amax: 0.20
λ: 270 nm Amax: 0.04
λ: 310-400 nm Amax: 0.01

SMILES 字串

[H]C(=O)OC

InChI

1S/C2H4O2/c1-4-2-3/h2H,1H3

InChI 密鑰

TZIHFWKZFHZASV-UHFFFAOYSA-N

尋找類似的產品? 前往 產品比較指南

一般說明

Methyl formate (MF) is one of the most significant intermediates in C1 chemistry. MF has been used to produce methanamide, N, N-dimethylformamide, dimethyl carbonate, methyl glycolate, acetic acid, ethylene glycol, methyl methacrylate, and high-purity CO. Additionally, MF can be used as a solvent for nitrocellulose and cellulose acetate.

應用


  • Bifunctionality of Re Supported on TiO(2) in Driving Methanol Formation in Low-Temperature CO(2) Hydrogenation.: This article explores the catalytic roles of methyl formate in methanol production from CO2 hydrogenation, providing a pathway for sustainable chemical synthesis (Urakawa A et al., 2023).

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 1 - STOT SE 1 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

-2.2 °F - closed cup

閃點(°C)

-19 °C - closed cup


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Katherine R Phillips et al.
Journal of the American Chemical Society, 135(2), 574-577 (2012-12-28)
Methyl formate is produced from the photo-oxidation of methanol on preoxidized TiO(2)(110). We demonstrate that two consecutive photo-oxidation steps lead to methyl formate using mass spectrometry and scanning tunneling microscopy. The first step in methanol oxidation is formation of methoxy
Methyl N-Phenyl Carbamate Synthesis from Aniline and Methyl Formate: Carbon Recycling to Chemical Products.
Yalfani MS, et al.
ChemSusChem, 8(3), 443-447 (2015)
Methyl formate as a carbonylating agent for the catalytic conversion of phenol to methyl phenyl carbonate.
Wu C, et al.
Green Chemistry, 17(3), 1467-1472 (2015)
Barriers to rotation adjacent to double bonds. 3. The carbon-oxygen barrier in formic acid, methyl formate, acetic acid, and methyl acetate. The origin of ester and amide resonance.
Wiberg KB and Laidig KE.
Journal of the American Chemical Society, 109(20), 5935-5943 (1987)
Microwave spectrum, barrier to internal rotation, and structure of methyl formate.
Curl Jr RF.
J. Chem. Phys. , 30(6), 1529-1536 (1959)

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