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Key Documents

63102

Sigma-Aldrich

高氯酸镁

puriss., free-flowing powder, ≥99.0% (calc. based on dry substance, KT)

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About This Item

線性公式:
Mg(ClO4)2
CAS號碼:
分子量::
223.21
EC號碼:
MDL號碼:
分類程式碼代碼:
12352300
PubChem物質ID:

等級

puriss.

化驗

≥99.0% (calc. based on dry substance, KT)

形狀

free flowing powder

品質

free-flowing powder

雜質

≤8% water

儲存溫度

room temp

SMILES 字串

[Mg++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O

InChI

1S/2ClHO4.Mg/c2*2-1(3,4)5;/h2*(H,2,3,4,5);/q;;+2/p-2

InChI 密鑰

MPCRDALPQLDDFX-UHFFFAOYSA-L

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一般說明

Magnesium perchlorate (Mg(ClO4)2) is widely used as drying agent for gases. It can remove water from gases (with no organic contaminants) at the rate of 0.001mgwater/l.

應用

干燥管的填充剂(尤其是用于元素分析)
Magnesium perchlorate (Mg(ClO4)2) may be employed as a catalyst in the following studies:
  • Preparation of a-aminophosphonates.
  • Enantioselective Diels-Alder reaction between cyclopentadiene and 3-acryloyl-1,3-oxazolin-2-one.
  • Preparation of imines and phenylhydrazones.
  • Protection of alcohols in the form of t-butyl ethers.

象形圖

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訊號詞

Danger

危險分類

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

5.1A - Strongly oxidizing hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable


分析證明 (COA)

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Giuseppe Bartoli et al.
Organic letters, 7(3), 427-430 (2005-01-28)
[reaction: see text] A new mild method for protecting alcohols as t-butyl ethers is reported. The reaction proceeds with Mg(ClO4)2 and Boc2O and shows general applicability. The deprotection of t-butyl ethers has also been revisited. Preliminary results indicate the CeCl3
Magnesium perchlorate as an efficient catalyst for the synthesis of imines and phenylhydrazones.
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Tetrahedron Letters, 45(41), 7641-7644 (2004)
The first enantioselective synthesis of both Diels-Alder enantiomers with the same bis (oxazoline)-magnesium perchlorate chiral catalyst.
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Commercially available magnesium perchlorate is reported as an extremely efficient catalyst for the synthesis of alpha-aminophosphonates. A three-component reaction (3-CR) of an amine, an aldehyde or a ketone, and a di-/trialkyl phosphite (Kabachnik-Fields reaction) took place in one pot under

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