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重要文件

209139

Sigma-Aldrich

硝酸银

ACS reagent, ≥99.0%

同義詞:

硝酸银(I)盐

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About This Item

線性公式:
AgNO3
CAS號碼:
分子量::
169.87
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.21

等級

ACS reagent

蒸汽密度

5.8 (vs air)

化驗

≥99.0%

形狀

solid

反應適用性

reagent type: catalyst
core: silver

溶膠的清晰度

passes test

雜質

Free acid, passes test
≤0.01% not HCl pptd.

mp

212 °C (dec.) (lit.)

負離子痕跡

chloride (Cl-): ≤5 ppm
sulfate (SO42-): ≤0.002%

正離子痕跡

Cu: ≤2 ppm
Fe: ≤2 ppm
Pb: ≤0.001%

SMILES 字串

[O-][N+]([O-])=O.[Ag+]

InChI

1S/Ag.NO3/c;2-1(3)4/q+1;-1

InChI 密鑰

SQGYOTSLMSWVJD-UHFFFAOYSA-N

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一般說明

硝酸银,又称硝酸银(I)盐,是一种无臭、无色或白色的多用途无机化合物,因其具有硬化、脱水和硬化的特性而被广泛用作氧化剂和烧灼剂。它通常用作有机硅烷水解氧化的催化剂,导致生产高产氢率和有机硅醇。

應用

硝酸银可用作催化剂:      
  • 用于苯衍生物的 Friedel-Crafts 酰化,以合成相应的酮类。     
  • 有机硅烷的水解氧化,以产生氢。

它可用于制备一些负载酸催化剂,以进行各种有机转化。例如:      
  • 基于 AgNO3–SiO2 的催化剂用于进行螺环化脱芳反应。      
  • 聚苯胺-AgNO3-PTSA(对甲苯磺酸)催化剂用于通过芳香醛、芳香胺和环己酮的三组分曼尼希反应合成抗-β-氨基酮。

AgNO3 也用作前体盐来合成银纳米颗粒。

訊號詞

Danger

危險分類

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Repr. 1B - Skin Corr. 1A

儲存類別代碼

5.1B - Oxidizing hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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