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重要文件

230731

Sigma-Aldrich

硝基甲烷

ReagentPlus®, ≥99.0%

同義詞:

Nitrocarbol

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About This Item

經驗公式(希爾表示法):
CH3NO2
CAS號碼:
分子量::
61.04
Beilstein:
1698205
EC號碼:
MDL號碼:
分類程式碼代碼:
12352102
PubChem物質ID:
NACRES:
NA.21
bp:
101.2 °C (lit.)

等級

reagent

蒸汽密度

2.1 (vs air)

蒸汽壓力

2.7 mmHg

產品線

ReagentPlus®

化驗

≥99.0%

形狀

liquid

自燃溫度

784 °F

expl. lim.

7.3 %, 33 °F

dilution

(for general lab use)

折射率

n20/D 1.382 (lit.)

pH值

6.4 (20 °C, 0.01 g/L)

bp

101.2 °C (lit.)

mp

−29 °C (lit.)

密度

1.127 g/mL at 25 °C (lit.)

SMILES 字串

C[N+]([O-])=O

InChI

1S/CH3NO2/c1-2(3)4/h1H3

InChI 密鑰

LYGJENNIWJXYER-UHFFFAOYSA-N

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一般說明

Nitromethane (CH3NO2) is the simplest nitro organic compound used for a wide range of applications, including as polar solvents to racing fuel. It serves as a solvent for organic chemistry and as a valuable building block for various useful compounds like nitroalkanes, β-nitroalcohols, nitroalkenes, carbonyl compounds, amines, and heterocycles. In industry, nitromethane can be used to stabilize halogenated hydrocarbons.

應用

Nitromethane can be used:
  • As a reagent in the synthesis of 3-nitroindoles by arylation with N-(2-bromoaryl) imidates using palladium catalyst.
  • As a cyanating reagent for the synthesis of thiocyanates in presence of base (KOAc) and iodine.
  • In the preparation of cobalt cage complexes from polyamines and formaldehyde.
  • As a solvent in the preparation of β-substituted γ-nitroaldehydes by enantioselective cross-coupling of β-arylated or γ,δ-unsaturated aldehydes using oxidizing agent DDQ (2,3-dichloro-5,6-dicyanoquinone) and catalyst diphenylprolinol silyl ether.

特點和優勢

Nitromethane as high energy monopropellant exhibits
  • Low toxicity.
  • High specific impulse.

法律資訊

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

訊號詞

Warning

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 3 - Repr. 2

儲存類別代碼

4.1A - Other explosive hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

95.0 °F - closed cup

閃點(°C)

35 °C - closed cup


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