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Merck
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重要文件

923133

Sigma-Aldrich

左旋葡萄糖酮

greener alternative

≥95%

同義詞:

(1S,5R)-6,8-二氧杂双环[3.2.1]辛-2-烯-4-酮, 1,6-脱水-3,4-双脱氧十六烷-3-烯吡喃-2-酮糖, 6,8-二氧杂双环[3.2.1]辛-2-烯-4-酮

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About This Item

經驗公式(希爾表示法):
C6H6O3
CAS號碼:
分子量::
126.11
MDL號碼:
分類程式碼代碼:
12352201
NACRES:
NA.22

品質等級

化驗

≥95%

形狀

liquid

環保替代產品特色

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

折射率

n/D 1.50625

密度

1.32 g/mL

官能基

ether
ketone

環保替代類別

儲存溫度

2-8°C

SMILES 字串

[H][C@]1(C=CC2=O)CO[C@]2([H])O1

InChI

1S/C6H6O3/c7-5-2-1-4-3-8-6(5)9-4/h1-2,4,6H,3H2/t4-,6+/m0/s1

InChI 密鑰

HITOXZPZGPXYHY-UJURSFKZSA-N

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相關類別

一般說明

We are committed to bringing you greener alternative products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is biorenewable and thus aligns with ″Safer Solvents and Auxiliaries″ and ″Use of Renewable Feedstocks″. Click here for more information.
Levoglucosenone undergoes Michael-addition reaction with diethyl malonate, ethyl cyanoacetate, 2-nitropropane and 2-methylcyclohexanone in the presence of various catalysts to afford 4-substituted levoglucosenone derivatives having the D-erythro configuration.

應用

Levoglucosenone may be used in the synthesis of the following:
  • Various deoxy, keto and branched-chain sugars
  • 4-thio and 4-substituted sugar derivatives
  • Natural stereoisomer of serricornin

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral - Eye Irrit. 2

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

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存取文件庫

Levoglucosenone and Its New Applications: Valorization of Cellulose Residues.
Comba M B, et al.
European Journal of Organic Chemistry, 590-604 (2018)
Jonas Kühlborn et al.
Natural product reports, 37(3), 380-424 (2019-10-19)
Covering: up to mid-2019 This review highlights the utilization of biomass-derived building blocks in the total synthesis of natural products. An overview over several renewable feedstock classes, namely wood/lignin, cellulose, chitin and chitosan, fats and oils, as well as terpenes
Recent Applications of Levoglucosenone as Chiral Synthon.
Sarotti A M, et al.
Current Organic Synthesis, 9(4), 439-459 (2012)

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