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83253

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三氟化硼-1-丁醇 溶液

~10% in 1-butanol (∼1.3 M), for GC derivatization, LiChropur

同義詞:

三氟化硼丁醇 溶液

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About This Item

CAS號碼:
MDL號碼:
分類程式碼代碼:
12000000
PubChem物質ID:
NACRES:
NA.05

等級

for GC derivatization

品質等級

形狀

solution

品質

LiChropur
for esterification of fatty acids for GC purposes

反應適用性

reagent type: derivatization reagent
reaction type: Alkylations

濃度

~10% in 1-butanol (∼1.3 M)

技術

gas chromatography (GC): suitable

密度

0.87 g/mL at 20 °C

儲存溫度

2-8°C

SMILES 字串

FB(F)F

InChI

1S/BF3/c2-1(3)4

InChI 密鑰

WTEOIRVLGSZEPR-UHFFFAOYSA-N

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應用

Learn more in the Product Information
Boron trifluoride-1-butanol solution may be used as a derivatization agent in the separation and identification of water‐soluble low‐molecular‐weight carboxylic acids using capillary electrophoresis (CE) and gas chromatography coupled with mass spectrometry (GC-MS).
Reagent for the esterification of carboxylic acids for GC analysis

法律資訊

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

訊號詞

Danger

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A - STOT SE 3

標靶器官

Central nervous system, Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

95.0 °F - closed cup

閃點(°C)

35 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Capillary electrophoresis determinative and GC-MS confirmatory method for water-soluble organic acids in airborne particulate matter and vehicle emission.
Dabek-Zlotorzynska E, et al.
Journal of Separation Science, 28(13), 1520-1528 (2005)
T Mizuno et al.
The Journal of chemical physics, 136(7), 074305-074305 (2012-03-01)
Recoil frame photoelectron angular distributions (RFPADs) of BF(3) molecules are presented over the energy region of the shape resonance in the F 1s continuum. Time-dependent density functional theory calculations are also given to understand the shape resonance dynamics. The RFPADs
The influence of the acidity of ionic liquids on catalysis.
Xinjiang Cui et al.
ChemSusChem, 3(9), 1043-1047 (2010-08-18)
Casey R Wade et al.
Chemical communications (Cambridge, England), 46(34), 6380-6381 (2010-08-07)
The presence of a proximal cationic group in zwitterionic aryltrifluoroborates such as o-(Ph(2)MeP)C(6)H(4)(BF(3)) stabilizes these compounds against hydrolysis.
Ramanathan Rajaganesh et al.
Carbohydrate research, 345(12), 1649-1657 (2010-06-29)
BF(3).Et(2)O-catalysed O-glycosylation of 1,2,3-tri-O-acetyl-4,6-O-butylidene- and ethylidene-beta-d-glucopyranose with different aliphatic and aromatic alcohols proceeds for the most part with complete retention of anomeric configuration. Antioxidant activity of O-glycosides shows significant inhibition (IC(50) approximately 77%). 1,3-Dipolar cycloaddition of terminal alkyne derivatives of

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