44920

乙酰丙酮铁 III

purum, ≥97.0% (RT)

• 同義詞: 2,4-戊二酮 铁(III) 衍生物, 2，4-戊二酮铁（III）, Fe(acac)₃, 乙酰丙酮铁
• 線性公式: Fe(C₅H₇O₂)₃
• CAS號碼: 14024-18-1
• 分子量：: 353.17
• Beilstein: 4157960
• EC號碼: 237-853-5
• MDL號碼: MFCD00000020
• 分類程式碼代碼: 12352103
• PubChem物質ID: 329756564
• NACRES: NA.23

屬性

• 等級: purum
• 品質等級: 200
• 化驗: ≥97.0% (RT)
• 形狀: powder
• 反應適用性: core: iron; reagent type: catalyst
• mp: 180-182 °C (dec.) (lit.); 180-190 °C (dec.)
• 密度: 5.24 g/mL at 25 °C (lit.)
• SMILES 字串: CC(=O)\C=C(\C)O[Fe](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O
• InChI: 1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;
• InChI 密鑰: AQBLLJNPHDIAPN-LNTINUHCSA-K

描述

一般說明

Iron(III) acetylacetonate, also known as tris(acetylacetonato)iron(III) or Fe(acac)₃, is a coordination compound that is highly soluble in organic solvents. It is used as a precursor in the preparation of iron-containing materials and thin films, which are important in electronics and coatings. Additionally, it is also as a catalyst in organic reactions, particularly in the synthesis of organic compounds and polymerization processes.

應用

用于高结晶（Zn，Fe）Fe₂O₄ 薄膜的 MOCVD 前体和这些薄膜的磁性测量。

Iron(III) acetylacetonate can be used as:     

• A precursor in the synthesis of Fe₃O₄/carbon composite fibers via forcespinning. This fiber material is suitable for use as anode materials in lithium-ion batteries.     
• A precursor in the synthesis of iron-based metal-organic frameworks (MOFs) for the applications in rechargeable alkali-ion batteries.
• A catalyst in the controlled living radical polymerization of vinyl acetate to synthesis of polymers with controlled molecular weights.   
• A precursor to synthesize iron-doped titania (Fe-TiO₂) photocatalysts for the potential applications in photocatalytic reactions.     
• A MOCVD precursor for highly crystalline (Zn,Fe)Fe₂O₄ films and magnetic property measurements of these films.

其他說明

用于格氏反应的催化剂，添加酸性氯化物可生成酮。

安全資訊

• 象形圖: GHS05,GHS07
• 訊號詞: Danger
• 危險聲明: H302 + H312 + H332,H318
• 防範說明: P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
• 危險分類: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves