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Key Documents

30620-M

Sigma-Aldrich

氢氧化钠

puriss. p.a., ACS reagent, reag. Ph. Eur., K ≤0.02%, ≥98%, pellets

同義詞:

‘苛性钠’

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About This Item

線性公式:
NaOH
CAS號碼:
分子量::
40.00
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.21

等級

ACS reagent
puriss. p.a.

品質等級

agency

reag. Ph. Eur.

蒸汽密度

>1 (vs air)

蒸汽壓力

<18 mmHg ( 20 °C)
3 mmHg ( 37 °C)

化驗

≥98%

形狀

pellets

技術

titration: suitable

雜質

≤0.0003% total nitrogen (N)
≤0.002% heavy metals (as Ag)
≤1.0% Na2CO3
≤5 ppm heavy metals (as Pb)

mp

318 °C (lit.)

溶解度

water: soluble 1260 g/L at 20 °C

密度

2.13 g/cm3

負離子痕跡

chloride (Cl-): ≤10 ppm
phosphate (PO43-): ≤0.0005%
silicate (as SiO2): ≤0.001%
sulfate (SO42-): ≤30 ppm

正離子痕跡

Al: ≤0.0005%
As: ≤0.0001%
Ca: ≤0.0005%
Cu: ≤0.0005%
Fe: ≤5 ppm
Hg: ≤0.05 ppm
K: ≤0.02%
Mg: ≤0.0005%
Ni: ≤0.0005%
Pb: ≤0.0002%
Zn: ≤0.0005%

SMILES 字串

[OH-].[Na+]

InChI

1S/Na.H2O/h;1H2/q+1;/p-1

InChI 密鑰

HEMHJVSKTPXQMS-UHFFFAOYSA-M

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一般說明

Sodium hydroxide is an inorganic base. It participates in the oxidation of glycerol, catalyzed by Au/charcoal or Au/graphite. It also participates in solvent-free aldol condensation reaction.

應用

Sodium hydroxide may be employed for determination of specific surface area of colloidal silica, via titration. It may be employed for direct oxidation of sodium borohydride, which was investigated by cyclic and linear voltammetry, chronoamperometry and chronopotentiometry. It may be used to compose citrate buffer and borate buffers.
It may be used in the synthesis of following compounds:
  • alkylaryl amidosulfobetaines
  • (3 -[4-teroctylphenoxyethoxyethoxyethyl] dimethylammonio propane sulfonate (XOSB)
  • trisulfobetaines (TriSBn)

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

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Silvio Carrettin et al.
Chemical communications (Cambridge, England), (7)(7), 696-697 (2002-07-18)
Glycerol is oxidised to glyceric acid with 100% selectivity using either 1% Au/charcoal or 1% Au/graphite catalyst under mild reaction conditions (60 degrees C, 3 h, water as solvent).

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