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Key Documents

00375

Sigma-Aldrich

4-乙酰氨-2,2,6,6-四甲基哌啶-1-氧

greener alternative

purum, ≥98.0% (HPLC)

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About This Item

經驗公式(希爾表示法):
C11H21N2O2
CAS號碼:
分子量::
213.30
Beilstein:
3546225
EC號碼:
MDL號碼:
分類程式碼代碼:
12352005
PubChem物質ID:
NACRES:
NA.22

等級

purum

品質等級

化驗

≥98.0% (HPLC)

環保替代產品評分

old score: 9
new score: 8
Find out more about DOZN™ Scoring

環保替代產品特色

Waste Prevention
Safer Solvents and Auxiliaries
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

143-145 °C (lit.)
143-146 °C

官能基

amide

環保替代類別

儲存溫度

2-8°C

SMILES 字串

CC(=O)NC1CC(C)(C)N([O])C(C)(C)C1

InChI

1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14)

InChI 密鑰

UXBLSWOMIHTQPH-UHFFFAOYSA-N

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相關類別

一般說明

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl undergoes one-electron oxidation and reduction reactions. Reaction products were analyzed by 1H, 13C and 15N NMR spectral data.
We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives . This product belongs to category of Re-engineered products, showing key improvements in Green Chemistry Principles “Waste Prevention”, “Safer Solvents and Auxiliaries” and “Inherently Safer Chemistry for Accident Prevention”. Click here to view its DOZN scorecard.

應用

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl radical may be employed in the catalytic system used for the regioselective oxidation of curdlan. It may be employed as model nitroxyl radical to study its reaction with thiophosgene. Reaction afforded 2,2,6,6-tetramethylpiperidine and 2,2,6,6-tetramethyl-1-hydroxypiperidine as major products.

其他說明

将醇轻度氧化成羰基的新型氧化剂

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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分析證明 (COA)

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客戶也查看了

A 1H, 13C and 15N NMR study of oxidation and reduction products of 4-acetamido-2, 2, 6, 6-tetramethylpiperidine-1-oxyl.
Schilf W, et al.
Journal of Molecular Structure, 407(1), 1-3 (1997)
Z. Ma et al.
The Journal of Organic Chemistry, 56, 6110-6110 (1991)
Reaction of Nitroxides with Sulfur Containing Compounds II [1]. Preparation of Nitroxides Bearing an Isothiocyanate Substituent in View of the Nitroxyl Group Reduction with Thiophosgene.
Zakrzewski J, et al.
Monatshefte fur Chemie / Chemical Monthly, 134(6), 843-850 (2003)
D Metodiewa et al.
Biochemistry and molecular biology international, 42(6), 1261-1270 (1997-09-26)
A novel complex, Rutoxyl [rutin/4-acetamide-1-hydroxy-2,2,6,6-tetramethylpiperidinium] was synthesized and its structure and anticancer activity were investigated. The results reported here are consistent with our idea, that the formation of such a complex of two biologically active molecules: polyphenolic flavonoid antioxidant (Rutin)
D Metodiewa et al.
Anticancer research, 19(2A), 1255-1260 (1999-06-16)
Since flavanone oximes derivatives (ethers) have been shown to modulate the growth of Yoshida Sarcoma cells in vivo and to induce apoptosis, the effects of these substances on immortalized cell lines growth were examined. Cell viability and sensitivity to investigated

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