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Key Documents

T44407

Sigma-Aldrich

三乙酰葡萄烯糖

98%

同義詞:

3,4,6-O-三乙酰基-D-葡萄糖烯, 三-O-乙酰基-D-葡萄烯糖

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About This Item

經驗公式(希爾表示法):
C12H16O7
CAS號碼:
分子量::
272.25
Beilstein:
90781
EC號碼:
MDL號碼:
分類程式碼代碼:
12352201
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

形狀

crystalline powder

光學活性

[α]25/D −12°, c = 2 in ethanol

mp

53-55 °C (lit.)

SMILES 字串

CC(=O)OC[C@H]1OC=C[C@@H](OC(C)=O)[C@@H]1OC(C)=O

InChI

1S/C12H16O7/c1-7(13)17-6-11-12(19-9(3)15)10(4-5-16-11)18-8(2)14/h4-5,10-12H,6H2,1-3H3/t10-,11-,12+/m1/s1

InChI 密鑰

LLPWGHLVUPBSLP-UTUOFQBUSA-N

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應用

用于低聚糖液相和固相合成的重要结构单元。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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Russell S Dahl et al.
Journal of the American Chemical Society, 126(27), 8356-8357 (2004-07-09)
This contribution describes the results of a new research effort in our laboratory aimed at the synthesis of novel aminoglycosides and amino-C-glycosides. Despite the importance of such compounds, and the previous development of some methodological solutions, this remains an important
Andreas H Franz et al.
The Journal of organic chemistry, 67(22), 7662-7669 (2002-10-26)
Lewis acid-catalyzed dimerization of mono- and disaccharidic per-O-acetylated glycals gave di- and tetrasaccharidic O-acetylated C-glycosides, respectively. 2,3-Enopyranosyl cyanides were obtained from per-O-acetylated glycals by a new, mild anomeric S(N)'-acetoxy displacement with Hg(CN)(2)/HgBr(2)/TMSCN. Per-O-acetylated 2-C-2-deoxy-pyranoses were converted into pyranosyl cyanides by
Clayton H Heathcock et al.
Journal of the American Chemical Society, 125(42), 12844-12849 (2003-10-16)
A multigram synthesis of the C29-C51 subunit of altohyrtin C (spongistatin 2) has been accomplished. Union of this intermediate with the C1-C28 fragment and further elaboration furnished the natural product. Completion of the C29-C51 subunit began with the aldol coupling
Oleksandr S Kanishchev et al.
Nucleosides, nucleotides & nucleic acids, 30(10), 768-783 (2011-10-05)
This paper offers the results of a synthesis and study of cytotoxicity and the anti-Epstein-Barr virus (EBV) activity of new 2-deoxy-2-chloro-pyranosyl derivatives of 4-tosyl-5-trifluoromethyl-1,2,3-triazole obtained via the addition reaction of the corresponding 2-N-chlorotriazole to the double bond of 3,4,6-tri-O-acetyl-D-glucal. Nucleoside
Application of molecular-mechanics calculations to D-glucal and its acetate; a comparison of X-ray and n.m.r. results.
W Korytnyk et al.
Carbohydrate research, 131(1), 157-165 (1984-08-01)

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