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Merck
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重要文件

CF0020

Sigma-Aldrich

4-Cyanophenoxytetrafluorobromoethane

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About This Item

線性公式:
C9H4BrF4NO
CAS號碼:
MDL號碼:
分類程式碼代碼:
12352101

形狀

liquid

反應適用性

reaction type: C-C Bond Formation

應用

4-Cyanophenoxytetrafluorobromoethane is a fluoroalkylbromide that is a radical source of the 4-cyanophenoxytetrafluoroethyl moiety. Alternatively, it can also be selectively metallated at the fluorinated carbon with Turbo Grignard reagent at low temperatures resulting in a thermally unstable anion that can act as a nucleophilic fluoroalkylation reagent towards a wide variety of electrophiles, such as aldehydes, ketones or sulfonylimines. The nitrile group can be transformed to other derivatives, building molecular complexity.

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法律資訊

Product of CF Plus Chemicals.

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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文章

The fluoroalkylation toolbox now includes Togni reagents, hypervalent iodine perfluoroalkylation reagents, fluoroalkyl bromides, silanes, carboxylates, and sulfonyl fluorides for late stage fluoroalkylation.

The fluoroalkylation toolbox now includes Togni reagents, hypervalent iodine perfluoroalkylation reagents, fluoroalkyl bromides, silanes, carboxylates, and sulfonyl fluorides for late stage fluoroalkylation.

The fluoroalkylation toolbox now includes Togni reagents, hypervalent iodine perfluoroalkylation reagents, fluoroalkyl bromides, silanes, carboxylates, and sulfonyl fluorides for late stage fluoroalkylation.

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