ALD00508

Yu Fluorination Ligand

≥95%

• 同義詞: 2,5,6,8-tetramethyl-3,4-dihydro-2H-pyrano[2,3-b]quinoline
• 經驗公式（希爾表示法）: C₁₆H₁₉NO
• CAS號碼: 1771764-64-7
• 分子量：: 241.33
• 分類程式碼代碼: 41116155
• PubChem物質ID: 329772697
• NACRES: NA.22

屬性

• 品質等級: 100
• 化驗: ≥95%
• 形狀: powder
• 反應適用性: reagent type: catalyst; reagent type: ligand; reaction type: C-H Activation
• SMILES 字串: CC1=C2C(OC(C)CC2)=NC3=C1C(C)=CC(C)=C3
• InChI: 1S/C16H19NO/c1-9-7-10(2)15-12(4)13-6-5-11(3)18-16(13)17-14(15)8-9/h7-8,11H,5-6H2,1-4H3
• InChI 密鑰: LOKRNFHHPZEJLL-UHFFFAOYSA-N

描述

一般說明

Yu Fluorination Ligand is widely employed for the chemoselective functionalization of sp²- and sp³ C-H bonds.

應用

The Yu Fluorination Ligand in tandem with Selectfluor(R) (Aldrich 439479) under palladium catalysis can promote direct fluorination of C(sp³)-H bonds stereoselectively. Yu and coworkers have displayed this on amino acid derivatives with directing group assistance from the Yu-Wasa Auxiliary (Aldrich 791806).

安全資訊

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable