ALD00378

Wasa-Yu MPAA Ligand

• 同義詞: (S)-3-(2,6-Difluorophenyl)-2-((((4-(trichloromethyl)heptan-4- yl)oxy)carbonyl)amino)propanoic acid
• 經驗公式（希爾表示法）: C₁₈H₂₂Cl₃F₂NO₄
• CAS號碼: 1346641-35-7
• 分子量：: 460.73
• 分類程式碼代碼: 12352101
• PubChem物質ID: 329772660
• NACRES: NA.22

屬性

• 形狀: solid
• 反應適用性: reaction type: C-H Activation; reagent type: catalyst; reagent type: ligand; reaction type: Peptide Synthesis
• bp: 521.1 °C±50.0 °C
• 密度: 1.365 g/cm³±0.06 g/cm³
• 官能基: amine; carboxylic acid
• 儲存溫度: 2-8°C
• SMILES 字串: O=C(O)[C@@H](NC(OC(CCC)(CCC)C(Cl)(Cl)Cl)=O)CC1=C(F)C=CC=C1F
• InChI: 1S/C18H22Cl3F2NO4/c1-3-8-17(9-4-2,18(19,20)21)28-16(27)24-14(15(25)26)10-11-12(22)6-5-7-13(11)23/h5-7,14H,3-4,8-10H2,1-2H3,(H,24,27)(H,25,26)/t14-/m0/s1
• InChI 密鑰: MYNBDMWXOQDYED-AWEZNQCLSA-N

描述

應用

The Wasa-Yu MPAA Ligand has been reported by Yu and coworkers to promote the enantioselective C-H activation of cyclopropanes. This transformation is carried out through the coupling of organoboron reagents using palladium-mediated catalysis.

其他說明

Pd(II)-Catalyzed Enantioselective C–H Activation of Cyclopropanes

安全資訊

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable