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Merck
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重要文件

A88255

Sigma-Aldrich

p-茴香胺

99%

同義詞:

4-氨基苯甲醚, 4-甲氧基苯胺

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About This Item

線性公式:
CH3OC6H4NH2
CAS號碼:
分子量::
123.15
Beilstein:
471556
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

99%

形狀

solid

自燃溫度

959 °F

bp

240-243 °C (lit.)

mp

56-59 °C (lit.)

SMILES 字串

COc1ccc(N)cc1

InChI

1S/C7H9NO/c1-9-7-4-2-6(8)3-5-7/h2-5H,8H2,1H3

InChI 密鑰

BHAAPTBBJKJZER-UHFFFAOYSA-N

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應用

在存在金催化剂的条件下,对茴香胺可进行有氧氧化,形成芳族偶氮化合物。
茴香胺可用于:
  • 在手性Bronsted酸催化下非对映选择性和对映选择性合成CF3-取代的偶氮啶。
  • 在Yb(OTf)3催化下,通过与乙醛酸乙酯和乙炔基(苯基)硒烷的多组分Povarov反应,制备4-有机硒基喹啉。
  • 作为分两步合成3-氟-6-甲氧基喹啉的原料。,
  • 以三氟甲磺酸银(I)为催化剂,通过与末端炔烃和二乙基甲酰基膦酸酯水合物反应制备N-PMP保护的α-氨基炔丙基膦酸酯。

訊號詞

Danger

危險分類

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Carc. 1B - STOT RE 2

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

251.6 °F - closed cup

閃點(°C)

122 °C - closed cup


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