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重要文件

A71301

Sigma-Aldrich

2-氨基苯酚

99%

同義詞:

(2-羟苯基)胺, 1-羟基-2-氨基苯, 2-氨基-1-羟基苯, 2-氨基苯基乙醇, 2-氨基苯酚, 2-羟基苯胺, 2-羟苯胺, o-氨基羟基苯, o-羟基苯胺, o-羟苯胺

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About This Item

線性公式:
H2NC6H4OH
CAS號碼:
分子量::
109.13
Beilstein:
606075
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

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品質等級

化驗

99%

形狀

powder

mp

170-175 °C (lit.)

SMILES 字串

Nc1ccccc1O

InChI

1S/C6H7NO/c7-5-3-1-2-4-6(5)8/h1-4,8H,7H2

InChI 密鑰

CDAWCLOXVUBKRW-UHFFFAOYSA-N

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本產品
P2443540025K4894
Poloxamer 188 solid

K4894

Poloxamer 188

mp

56-61 °C

mp

-

mp

-

mp

-

impurities

≤0.5% water

impurities

-

impurities

<200 μM aldehyde, <200 μM peroxide, 10%±1 detergent

impurities

-

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

200

hydroxyl value

6‑9 mg KOH/g

hydroxyl value

-

hydroxyl value

-

hydroxyl value

-

應用

2-氨基苯酚可用于合成:
  • 与β氨基醇在Pd/C-I2催化下通过氧化环羰基化反应合成2-噁唑烷酮衍生物。[1]
  • 与亚水杨基-4-氨基安替比林合成席夫碱过渡金属(II)配合物。[2]
  • 在富氧气氛、活性碳催化下与醛合成2-芳基苯并噁唑。[3]

象形圖

Health hazardExclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Muta. 2

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 2

閃點(°F)

334.4 °F - closed cup

閃點(°C)

168 °C - closed cup

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Synthesis of 2-oxazolidinone catalyzed by palladium on charcoal: a novel and highly effective heterogeneous catalytic system for oxidative cyclocarbonylation of β -aminoalcohols and 2-aminophenol.
Li F and Xia C
J. Catal., 227(2), 542-546 (2004)
Synthesis, spectroscopic characterization, redox, and biological screening studies of some Schiff base transition metal (II) complexes derived from salicylidene-4-aminoantipyrine and 2-aminophenol/2-aminothiophenol.
Raman N, et al.
Synth. React. Inorg. Met.-Org. Chem. , 31(7), 1249-1270 (2001)
Bifu Liu et al.
Chemical communications (Cambridge, England), 48(93), 11446-11448 (2012-10-23)
A robust route to 4-amine-benzo[b][1,4]oxazepines relying upon a palladium-catalyzed tandem reaction of o-aminophenols, bromoalkynes and isocyanides has been developed. This chemistry presumably proceeds through the migratory insertion of isocyanides into the vinyl-palladium intermediate as a key step.
Anangamohan Panja et al.
Dalton transactions (Cambridge, England : 2003), 42(14), 5068-5075 (2013-02-12)
A bis(imido)-bridged dinuclear cobalt(III) complex, [Co2(amp)2(μ-imp)2Cl2]Cl2·2H2O () [amp = 2-aminomethylpyridine; imp = 2-iminomethylpyridine anion], was synthesized by the reaction of cobalt(II) chloride with 2-aminomethylpyridine in the presence of alkaline hydrogen peroxide at room temperature. X-ray crystallography reveals that both the
Ru Chen et al.
Organic & biomolecular chemistry, 9(22), 7675-7679 (2011-09-23)
A palladium-catalyzed desulfitative C-H arylation of azoles with sodium sulfinates using Cu(OAc)(2)·H(2)O as oxidant has been discovered. The reaction proceeded well for a range of different substrates under oxidative conditions. A series of aryl-substituted azoles have been synthesized in moderate

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