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Merck
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重要文件

A15401

Sigma-Aldrich

丁炔二酸 单钾盐

≥98%

同義詞:

2-丁炔二酸单钾盐

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About This Item

線性公式:
HOOCC≡CCOOK
CAS號碼:
分子量::
152.15
Beilstein:
3571639
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥98%

形狀

powder

SMILES 字串

[K+].OC(=O)C#CC([O-])=O

InChI

1S/C4H2O4.K/c5-3(6)1-2-4(7)8;/h(H,5,6)(H,7,8);/q;+1/p-1

InChI 密鑰

KLLYWRUTRAFSJT-UHFFFAOYSA-M

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象形圖

Skull and crossbones

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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分析證明 (COA)

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Heiner Eckert
Molecules (Basel, Switzerland), 17(1), 1074-1102 (2012-01-24)
A collection of smart multicomponent reactions (MCRs) with continuative post condensation cyclizations (PCCs) is presented to construct conventional three- to seven-membered heterocyclic compounds in diversity oriented syntheses (DOS). These will provide a high degree of applying economical and ecological advantages
Issa Yavari et al.
Molecular diversity, 10(2), 265-270 (2006-06-17)
Protonation of the reactive intermediates produced in the reaction between alkyl(aryl) isocyanides and dialkyl acetylenedicarboxylates by indan-1,3-dione leads to vinylnitrilium cations, which undergo carbon centered Michael type addition with the conjugate base of the CH-acid to produce functionalized 5-oxo-4,5-dihydroindeno[1,2-b]pyrans.
A S Subbaraman et al.
Origins of life, 10(4), 343-347 (1980-12-01)
A number of routes have been suggested for the prebiotic synthesis of uracil involving the reaction of urea with malic acid, propiolic acid, cyanoacetylene and others. Cyanoacetylene has been detected in the interstellar medium as well as simulated prebiotic experiments.
Lothar Brecker et al.
European journal of biochemistry, 270(7), 1393-1398 (2003-03-26)
Only 2% of the known natural products with acetylenic bonds are alpha-alkynoates. Their polarized, conjugated triple bond is an optimal target for an enzymic hydration. Therefore they are good substrates for the enzymes involved in metabolism of acetylenic compounds, resulting
Identification of an intermediate in the de novo formation of nicotinamide adenine dinucleotide in Escherichia coli.
J T Heard et al.
Biochemical and biophysical research communications, 95(4), 1517-1521 (1980-08-29)

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