912794

Ni(COD)(DQ)

≥95%

• 同義詞: Bis(1,5-cyclooctadiene)(duroquinone) nickel(0)
• 經驗公式（希爾表示法）: C₁₈H₂₄NiO₂
• CAS號碼: 40759-64-6
• 分子量：: 331.08
• MDL號碼: MFCD32851669
• 分類程式碼代碼: 12352103
• NACRES: NA.22

屬性

• 品質等級: 100
• 化驗: ≥95%
• 形狀: powder
• 反應適用性: reagent type: catalyst; reaction type: Cross Couplings
• 參數: temperature stable
• mp: 227 °C (decomposition)
• SMILES 字串: [Ni](C)C.O=C2C(=C(C(=O)C(=C2C)C)C)C.C1CCC\C=C/CC1
• InChI 密鑰: PRUJUYLPWIUASG-ZMKTYRQVSA-N

描述

應用

Ni(COD)(DQ), as shown by the Engle lab, is an air- and thermally stable Ni(0) precatalyst. This 18-electron complex has a unique stability profile allowing for easy reaction setup outside an inert atmosphere. Transformations such as the Suzuki-Miyaura coupling, borylation of aryl halides, and alkene hydroarylation have been demonstrated.

其他說明

Ni(COD)(DQ): An Air-Stable 18-Electron Ni(0)–Olefin Precatalyst

安全資訊

• 象形圖: GHS08,GHS07
• 訊號詞: Danger
• 危險聲明: H317,H351,H372
• 防範說明: P201 - P280 - P302 + P352 - P308 + P313
• 危險分類: Carc. 2 - Skin Sens. 1 - STOT RE 1
• 標靶器官: Lungs
• 儲存類別代碼: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable