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912727

Sigma-Aldrich

(2R,3R)-iPr-BIDIME

同義詞:

(2R,3R)-3-(Tert-butyl)-4-(2,6-dimethoxyphenyl)-2-isopropyl-2,3-dihydrobenzo[d][1,3]oxaphosphole

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About This Item

經驗公式（希爾表示法）:
C22H29O3P
CAS號碼:
1477517-19-3
分子量：:
372.44
MDL號碼:
MFCD31630762
分類程式碼代碼:
12352200
NACRES:
NA.22

形狀

powder and chunks

品質等級

100

光學純度

ee: ≥99% (HPLC)

反應適用性

reagent type: ligand

官能基

phosphine

SMILES 字串

P1([C@@H](Oc2c1c(ccc2)c3c(cccc3OC)OC)C(C)C)C(C)(C)C

InChI

1S/C22H29O3P/c1-14(2)21-25-18-13-8-10-15(20(18)26(21)22(3,4)5)19-16(23-6)11-9-12-17(19)24-7/h8-14,21H,1-7H3/t21-,26?/m1/s1

InChI 密鑰

AVUPKIFOTAYCAC-OSMGYRLQSA-N

相關類別

應用

(2R,3R)-iPr-BIDIME is a P-chiral monophosphorus ligand used for the transition metal-catalyzed asymmetric Suzuki-Miyaura and hydroboration reactions.

其他說明

Synthesis of Chiral α-Amino Tertiary Boronic Esters by Enantioselective Hydroboration of α-Arylenamides

法律資訊

Sold in collaboration with Zejun Pharmaceuticals

相關產品

產品號碼
描述
訂價

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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分析證明 (COA)

Lot/Batch Number

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Guangqing Xu et al.
Journal of the American Chemical Society, 136(2), 570-573 (2013-10-24)
Efficient asymmetric Suzuki-Miyaura coupling reactions are employed for the first time in total syntheses of chiral biaryl natural products korupensamine A and B in combination with an effective diastereoselective hydrogenation, allowing ultimately a concise and stereoselective synthesis of michellamine B.
Naifu Hu et al.
Journal of the American Chemical Society, 137(21), 6746-6749 (2015-05-06)
The rhodium-catalyzed asymmetric hydroboration of α-arylenamides with BI-DIME as the chiral ligand and (Bpin)2 as the reagent yields for the first time a series of α-amino tertiary boronic esters in good yields and excellent enantioselectivities (up to 99% ee).

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