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Merck
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重要文件

908576

Sigma-Aldrich

WinterGreen photocage

≥95%

同義詞:

(1,3,5,5,7,9-Hexamethyl-dipyrrolo[1,3,2]diazaborinin-10-yl)methanol, 4,4′-Dimethyl-8-hydroxymethyl-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene, BODIPY photocage, Imidazole-protected BODIPY alcohol

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About This Item

經驗公式(希爾表示法):
C16H23BN2O
CAS號碼:
分子量::
270.18

化驗

≥95%

形狀

powder or crystals

儲存溫度

2-8°C

應用

Green-light absorbing photocage. Easily functionalized to ester with DCC/EDC couplings for photorelease of carboxylic acids.

法律資訊

US Patent Application #16/140,218

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

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Tomáš Slanina et al.
Journal of the American Chemical Society, 139(42), 15168-15175 (2017-10-19)
A detailed investigation of the photophysical parameters and photochemical reactivity of meso-methyl BODIPY photoremovable protecting groups was accomplished through systematic variation of the leaving group (LG) and core substituents as well as substitutions at boron. Efficiencies of the LG release
Pratik P Goswami et al.
Journal of the American Chemical Society, 137(11), 3783-3786 (2015-03-10)
Photoremovable protecting groups derived from meso-substituted BODIPY dyes release acetic acid with green wavelengths >500 nm. Photorelease is demonstrated in cultured S2 cells. The photocaging structures were identified by our previously proposed strategy of computationally searching for carbocations with low-energy

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