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904716

Sigma-Aldrich

(CAAC-Cy)Rh(COD)Cl

同義詞:

[2-[2,6-bis(1-methylethyl)phenyl]-3,3-dimethyl-2-azaspiro[4.5]dec-1-ylidene]chloro[(1,2,5,6-η)-1,5-cyclooctadiene]Rhodium

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About This Item

經驗公式（希爾表示法）:
C31H47ClNRh
CAS號碼:
1801869-83-9
分子量：:
572.07
MDL號碼:
MFCD11978024
分類程式碼代碼:
12352101
NACRES:
NA.22

形狀

powder or crystals

儲存溫度

−20°C

相關類別

應用

(CAAC-Cy)Rh(COD)Cl is a selective hydrogenation catalyst used for the hydrogenation of a variety of arenes including fluoroarenes giving access to all-cis-multifluorinated cycloalkanes.1

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其他說明

Highly Selective Hydrogenation of Aromatic Ketones and Phenols Enabled by Cyclic (Amino)(alkyl)carbene Rhodium Complexes

Hydrogenation of fluoroarenes: Direct access to all-cis-(multi)fluorinated cycloalkanes

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產品號碼
描述
訂價

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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分析證明 (COA)

Lot/Batch Number

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Mario P Wiesenfeldt et al.
Angewandte Chemie (International ed. in English), 57(27), 8297-8300 (2018-05-24)
We report a method to convert readily available silylated arenes into silylated saturated carbo- and heterocycles by arene hydrogenation. The scope includes alkoxy- and halosilyl substituents. Silyl groups can be derivatized into a plethora of functionalities and find application in
Yu Wei et al.
Journal of the American Chemical Society, 137(29), 9250-9253 (2015-07-15)
Air-stable Rh complexes ligated by strongly σ-donating cyclic (amino)(alkyl)carbenes (CAACs) show unique catalytic activity for the selective hydrogenation of aromatic ketones and phenols by reducing the aryl groups. The use of CAAC ligands is essential for achieving high selectivity and
Mario P Wiesenfeldt et al.
Science (New York, N.Y.), 357(6354), 908-912 (2017-08-12)
All-cis-multifluorinated cycloalkanes exhibit intriguing electronic properties. In particular, they display extremely high dipole moments perpendicular to the aliphatic ring, making them highly desired motifs in material science. Very few such motifs have been prepared, as their syntheses require multistep sequences

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