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Merck
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重要文件

901267

Sigma-Aldrich

Hexamethylborazine

≥95%

同義詞:

1,2,3,4,5,6-Hexamethyl-1,3,5,2,4,6-triazatriborinane

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About This Item

經驗公式（希爾表示法）:
C6H18B3N3
CAS號碼:
877-07-6
分子量：:
164.66
MDL號碼:
MFCD00161355
分類程式碼代碼:
12161600
NACRES:
NA.22

品質等級

100

化驗

≥95%

形狀

powder or crystals

反應適用性

core: boron
reagent type: catalyst

mp

99 °C

儲存溫度

−20°C

SMILES 字串

B1(N(B(N(B(N1C)C)C)C)C)C

InChI

1S/C6H18B3N3/c1-7-10(4)8(2)12(6)9(3)11(7)5/h1-6H3

InChI 密鑰

LCHQMXUQYONIOI-UHFFFAOYSA-N

應用

Hexamethylborazine has been developed by the Szymczak lab for the delivery of alkyl and hydride nucleophiles in addition to being a key component in the synthesis of recyclable trifluoromethylation reagents.

其他說明

Recyclable Trifluoromethylation Reagents from Fluoroform

Manganese-mediated hydride delivery to a borazine by stepwise reduction and protonation

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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分析證明 (COA)

Lot/Batch Number

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Tyler J Carter et al.
Angewandte Chemie (International ed. in English), 51(52), 13168-13172 (2012-11-20)
Recharging spent BN fuel: {Cr(CO)(3)} mediates the reduction of borazines by hydride and methyl nucleophiles to generate anionic complexes of dearomatized hexamethylborazine. Subsequent quenching leads to the release of a substituted cyclotriborazane, successfully demonstrating the stepwise reduction of a B=N
Borazine?CF3? Adducts for Rapid, Room Temperature, and Broad Scope Trifluoromethylation.
Geri J B, et al.
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 130(5), 1395-1399 (2018)
Reduction of Borazines Mediated by Low?Valent Chromium Species.
Carter T J, et al.
Angewandte Chemie (International Edition in English), 51(52), 13168-13172 (2012)
Manganese-Mediated Hydride Delivery to a Borazine by Stepwise Reduction and Protonation.
Carter T J, et al.
Organometallics, 33(7), 1540-1543 (2014)
Anna S Lisovenko et al.
Inorganic chemistry, 49(22), 10357-10369 (2010-10-23)
Donor-acceptor complexes of borazine (BZ) and its substituted derivatives with Lewis acids (A = MCl(3), MBr(3); M = B, Al, Ga) and Lewis bases (D = NH(3), Py) have been theoretically studied at the B3LYP/TZVP level of theory. The calculations
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