推薦產品
品質等級
化驗
≥95%
形狀
powder or solid
反應適用性
core: nickel
reaction type: Cross Couplings
reagent type: catalyst
reaction type: Asymmetric synthesis
SMILES 字串
CC(C)(C)P(C(C)(C)C)C[C]1[C][C][C][C]1P(C2=CC=CC=C2)C3=CC=CC=C3.[Ni+2]C4=CC=C(C#N)C=C4.[C]5[C][C][C][C]5.[Fe]
應用
Amination of aryl chlorides with ammonia.
訊號詞
Warning
危險聲明
危險分類
Aquatic Chronic 2 - Repr. 2 - Skin Irrit. 2
儲存類別代碼
4.1B - Flammable solid hazardous materials
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
Ni?Catalyzed Amination Reactions: An Overview.
Chemical Record, 16(4), 1819-1832 (2016)
Nickel?Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts.
Angewandte Chemie (International Edition in English), 54(12), 3768-3772 (2015)
Evaluating 1, 1?-Bis (phosphino) ferrocene Ancillary Ligand Variants in the Nickel-Catalyzed C?N Cross-Coupling of (Hetero) aryl Chlorides.
Organometallics, 36(3), 679-686 (2017)
Nickel?Catalyzed Monoarylation of Ammonia.
Angewandte Chemie (International Edition in English), 54(12), 3773-3777 (2015)
Nature, 509(7500), 299-309 (2014-05-16)
Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready access to multiple oxidation states, have allowed the development of a broad range of innovative reactions.
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