923524

(tBuMPhos)PdCl₂

• 同義詞: 1-Diadamantylphosphino-1′-di-tert-butylphosphinoferrocene palladium dichloride
• 經驗公式（希爾表示法）: C₃₈H₅₆Cl₂FeP₂Pd
• 分子量：: 807.97
• 分類程式碼代碼: 12352200
• NACRES: NA.21

屬性

• 形狀: powder
• 品質等級: 100
• 環保替代產品特色: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• 環保替代類別: Aligned
• SMILES 字串: [Cl-][Pd+2]1([Cl-])[P](C(C)(C)C)(C(C)(C)C)[C-]23[CH]4=[CH]5[CH]6=[CH]2[Fe+2]56789%1043[CH]=%11[CH]%10=[CH]9[C-]8([CH]%117)[P]1(C%12%13CC%14CC(CC(C%14)C%12)C%13)C%15%16CC%17CC(CC(C%17)C%15)C%16
• InChI: InChI=1S/C25H34P.C13H22P.2ClH.Fe.Pd/c1-2-4-23(3-1)26(24-11-17-5-18(12-24)7-19(6-17)13-24)25-14-20-8-21(15-25)10-22(9-20)16-25;1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;;;;/h1-4,17-22H,5-16H2;7-10H,1-6H3;2*1H;;/q2*-1;;;2*+2/p-2
• InChI 密鑰: BJILVUSTVVKBGK-UHFFFAOYSA-L

描述

一般說明

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

應用

(tBuMPhos)PdCl₂ is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing CyMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

其他說明

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

安全資訊

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable