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763004

Sigma-Aldrich

CPhos Pd G3

95%

同義詞:

CPhos-G3-环钯配合物, CPhos-Pd-G3, [(2-二环己基膦基-2′,6′-双(N,N-二甲基氨) -1,1′-联苯)-2-(2′-氨基-1,1′-联苯)] 甲磺酸钯(II)

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About This Item

經驗公式(希爾表示法):
C41H54N3O3PPdS
CAS號碼:
分子量::
806.34
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

95%

形狀

solid

特點

generation 3

反應適用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

mp

176-178 °C (decomposition)

官能基

phosphine

SMILES 字串

CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CN(C)c3cccc(N(C)C)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6

InChI

1S/C28H41N2P.C12H10N.CH4O3S.Pd/c1-29(2)25-19-13-20-26(30(3)4)28(25)24-18-11-12-21-27(24)31(22-14-7-5-8-15-22)23-16-9-6-10-17-23;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h11-13,18-23H,5-10,14-17H2,1-4H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1

InChI 密鑰

SMFSVINURNWOPR-UHFFFAOYSA-M

一般說明

CPhos Pd G3 是改良型G3预催化剂(G3′)。它由Buchwald和同事利用第二代(G2)预催化剂,通过联苯骨架上的氨基的甲基化反应合成的。它是各种交叉偶联反应的有效催化剂。他们是一种通用催化剂,可长期以溶液形式储存,并且易溶于各种有机溶剂。G3-预催化剂已被用于各种C-N键形成反应。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

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存取文件庫

2-Aminobiphenyl Palladacycles: The ?Most Powerful? Precatalysts in C-C and C-Heteroatom Cross-Couplings.
Bruneau A, et al.
ACS Catalysis, 5(2), 1386-1396 (2015)

文章

All of the preformed catalysts used in the kit are air and moisture stable complexes in their commercially available form. Once activated by base under the reaction conditions they become sensitive to air. To best enable scale-up success, the use of standard Schlenk technique is recommended.

All of the preformed catalysts used in the kit are air and moisture stable complexes in their commercially available form. Once activated by base under the reaction conditions they become sensitive to air. To best enable scale-up success, the use of standard Schlenk technique is recommended.

All of the preformed catalysts used in the kit are air and moisture stable complexes in their commercially available form. Once activated by base under the reaction conditions they become sensitive to air. To best enable scale-up success, the use of standard Schlenk technique is recommended.

All contents in the foil bag are weighed, plated, packed, and sealed in a glove box under nitrogen.

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