675202
Tetrakis(hexahydro-2H-pyrimido[1,2-a]pyrimidinato)ditungsten(III) dichloride
同義詞:
Tetrakis(1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinate)ditungsten(III) dichloride, Tetrakis(1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinato)ditungsten(III) dichloride, W2(hpp)4Cl2
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About This Item
線性公式:
W2(C7H12N3)4Cl2
CAS號碼:
分子量：:
991.35
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22
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形狀
solid
品質等級
反應適用性
core: tungsten
reagent type: catalyst
mp
233-235 °C
SMILES 字串
C12=NCCCN1CCCN2[W-]3([Cl+][W-](N4C5=NCCCN5CCC4)(N6C7=NCCCN7CCC6)[Cl+]3)N8C9=NCCCN9CCC8
InChI
1S/4C7H12N3.2Cl.2W/c4*1-3-8-7-9-4-2-6-10(7)5-1;;;;/h4*1-6H2;;;;/q4*-1;4*+1
InChI 密鑰
ULSLYQPHFUUSFQ-UHFFFAOYSA-N
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
分析證明 (COA)
輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號，寫有 ‘Lot’或‘Batch’.。
F Albert Cotton et al.
Inorganic chemistry, 45(1), 201-213 (2006-01-05)
A far superior synthesis is reported for W(2)(hpp)(4)Cl(2), a key intermediate in the synthesis of the most easily ionized closed-shell molecule W(2)(hpp)(4) (hpp = the anion of the bicyclic guanidine compound 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine). At 200 degrees C, the one-pot reaction of
F Albert Cotton et al.
Journal of the American Chemical Society, 127(31), 10808-10809 (2005-08-04)
A new synthetic path, far superior to either of those previously available, to the W2(hpp)4 molecule (Hhpp = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine) is reported. The reaction of W(CO)6 with Hhpp in o-dichlorobenzene at 200 degrees C produces W2(hpp)4Cl2 in a one-pot reaction in
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