673013

2-苄氧基苯基溴化镁 溶液

1.0 M in THF

• 經驗公式（希爾表示法）: C₁₃H₁₁BrMgO
• CAS號碼: 328000-16-4
• 分子量：: 287.43
• MDL號碼: MFCD08705262
• 分類程式碼代碼: 12352103
• PubChem物質ID: 24885138
• NACRES: NA.22

屬性

• 反應適用性: reaction type: Grignard Reaction
• 品質等級: 100
• 濃度: 1.0 M in THF
• 密度: 1.047 g/mL at 25 °C
• 官能基: phenyl
• SMILES 字串: Br[Mg]c1ccccc1OCc2ccccc2
• InChI: 1S/C13H11O.BrH.Mg/c1-3-7-12(8-4-1)11-14-13-9-5-2-6-10-13;;/h1-9H,11H2;1H;/q;;+1/p-1
• InChI 密鑰: VELKJPFZDYXBDE-UHFFFAOYSA-M

描述

應用

2-Benzyloxyphenylmagnesium bromide can be used:

• As a substrate in the iron-catalyzed coupling reaction of aryl Grignard reagents with unprotected bromophenols.
• As a substrate in the cross-coupling of Grignard reagents using diaryl titanates and ferric chloride.
• In one of the key synthetic steps for the total synthesis of an antibiotic caboxamycin.

安全資訊

• 象形圖: GHS02,GHS08,GHS05,GHS07
• 訊號詞: Danger
• 危險聲明: H225,H302,H314,H335,H351
• 防範說明: P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• 危險分類: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• 標靶器官: Respiratory system
• 安全危害: EUH014,EUH019
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: -4.0 - 5.0 °F - closed cup
• 閃點（°C）: -20 - -15 °C - closed cup
• 個人防護裝備: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter