563749

9-菲基溴化镁

0.5 M in THF

• 經驗公式（希爾表示法）: C₁₄H₉BrMg
• CAS號碼: 71112-64-6
• 分子量：: 281.43
• MDL號碼: MFCD00672008
• 分類程式碼代碼: 12352103
• PubChem物質ID: 24880126
• NACRES: NA.22

屬性

• 反應適用性: reaction type: Grignard Reaction
• 品質等級: 100
• 濃度: 0.5 M in THF
• bp: 65 °C (lit.)
• 密度: 0.970 g/mL at 25 °C (lit.)
• 儲存溫度: 2-8°C
• SMILES 字串: Br[Mg]c1cc2ccccc2c3ccccc13
• InChI: 1S/C14H9.BrH.Mg/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13;;/h1-9H;1H;/q;;+1/p-1
• InChI 密鑰: ACMUZKQPXSHTGB-UHFFFAOYSA-M

描述

一般說明

9-phenanthrylmagnesium bromide is a Grignard reagent. It can be prepared using magnesium turnings and 9-bromophenanthrene under anhydrous condition.

應用

9-Phenanthrylmagnesium bromide can be used as a reagent to prepare:

• 9-alkyl and 9-arylthiophenanthrenes by reacting with alkyl or aryl thiol compounds.
• (S)-α-methylbenzyl 1-(9-phenanthryl)-2-naphthoate by treating with (S)- α -methylbenzyl methoxy-2-naphthoate.
• 1-(9-Phenanthryl)-1-phenylethanol (carbinol) by reacting with acetophenone. The obtained carbinol undergoes dehydration reaction in the presence of acetic acid and sulfuric acid to afford 1-(9-phenanthryl)-1-phenylethene (PPE).

法律資訊

Rieke ® Metals, Inc. 的产品，®Rieke Metals, Inc. 的注册商标

安全資訊

• 象形圖: GHS02,GHS08,GHS07
• 訊號詞: Danger
• 危險聲明: H225,H302,H319,H335,H351
• 防範說明: P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• 危險分類: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 安全危害: EUH019
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable