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671274

(R,R)-(-)-N,N′-二甲基-1,2-环己二胺

Name: (R,R)-(-)-N,N′-二甲基-1,2-环己二胺
Brand: ALDRICH

≥97.0% (GC)

同義詞:

(R,R)-(-)-N,N′-二甲基-1,2-二氨基环己烷, 反式-1,2-双(甲氨基)环己烷

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About This Item

經驗公式（希爾表示法）:

C₈H₁₈N₂

CAS號碼:

68737-65-5

分子量：:

142.24

MDL號碼:

MFCD00671527

分類程式碼代碼:

12352116

PubChem物質ID:

24885095

NACRES:

NA.22

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化驗

≥97.0% (GC)

光學活性

[α]/D -145±5°, c = 4.47 in chloroform

mp

39-44 °C

官能基

amine

儲存溫度

2-8°C

SMILES 字串

CN[C@@H]1CCCC[C@H]1NC

InChI

1S/C8H18N2/c1-9-7-5-3-4-6-8(7)10-2/h7-10H,3-6H2,1-2H3/t7-,8-/m1/s1

InChI 密鑰

JRHPOFJADXHYBR-HTQZYQBOSA-N

一般說明

(R,R)-(-)-N,N′-Dimethyl-1,2-cyclohexanediamine is a N,N′-dimethylated derivative of enantiopure 1,2-diaminocyclohexane. It can be formed during the hydrolysis of (R_3a,R_7a)-1,3-(dimethyl)-2-phenyl-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3,2-benzodiazaphosphole 2-oxide using HCl-methanol.

應用

(R,R)-(−)-N,N′-Dimethyl-1,2-cyclohexanediamine can be used:

As a ligand in the preparation of 4H-benzo[f]imidazo[1,4]diazepin-6-one through multi-component Ullmann coupling reaction.
In one of the key synthetic steps for the preparation of tricyclic γ-secretase modulators.
To prepare chiral fluorous diamino-diol proligand, which is used in the synthesis of zirconium metal complexes applicable as catalysts in 1-hexene polymerization.