推薦產品
品質等級
化驗
97%
光學活性
[α]20/D +102°, c = 1 in ethanol
光學純度
ee: 99% (GLC)
mp
79-83 °C (lit.)
SMILES 字串
N[C@@H]([C@H](N)c1ccccc1)c2ccccc2
InChI
1S/C14H16N2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-14H,15-16H2/t13-,14-/m1/s1
InChI 密鑰
PONXTPCRRASWKW-ZIAGYGMSSA-N
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應用
通用应用:
- (1R,2R)-(+)-1,2-二苯基乙二胺(DPEN)是一种广泛使用的手性助剂和配体,用于合成不对称催化剂,如 BINAP /二胺-Ru 络合物,用于立体选择性加氢。
- 它可用于制备单磺酰基 DPEN-盐,用于催化各种酮类向马来酰亚胺的迈克尔加成反应。
- DPEN 衍生的手性三唑盐可用于催化对映选择性分子内的 Stetter 反应和氧二烯 狄尔斯-阿德尔反应。
- 醋酸锌配合物 DPEDA 衍生的配体也可用于催化亚胺的氢化硅烷化。
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
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