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667897

Sigma-Aldrich

1,2-二乙氧基-1,1,2,2-四甲基二硅烷

97%

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About This Item

線性公式:
((CH3CH2O)(CH3)2Si)2
CAS號碼:
18419-84-6
分子量：:
206.43
MDL號碼:
MFCD08276886
分類程式碼代碼:
12352103
PubChem物質ID:
24884946
NACRES:
NA.22

品質等級

100

化驗

97%

折射率

n20/D 1.423

bp

84 °C/50 mmHg

密度

0.836 g/mL at 25 °C

SMILES 字串

CCO[Si](C)(C)[Si](C)(C)OCC

InChI

1S/C8H22O2Si2/c1-7-9-11(3,4)12(5,6)10-8-2/h7-8H2,1-6H3

InChI 密鑰

GWIVSKPSMYHUAK-UHFFFAOYSA-N

相關類別

應用

二硅烷试剂，用于制备二甲基硅醇交叉偶联配偶体。

象形圖

Flame
GHS02

訊號詞

Warning

危險聲明

H226

危險分類

Flam. Liq. 3

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

107.6 °F

閃點（°C）

42 °C

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

分析證明 (COA)

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Scott E Denmark et al.
Organic letters, 5(19), 3483-3486 (2003-09-12)
[reaction: see text] A mild and general palladium-catalyzed insertion of 1,2-diethoxy-1,1,2,2-tetramethyldisilane into a variety of aryl bromides affords the aryldimethylsilyl ethers in high yields. Hydrolysis of the ethers under pH-optimized conditions results in the exclusive formation of the desired aryldimethylsilanols.

文章

Organosilanols

Over the past several years, the Pd-catalyzed cross-coupling of silicon compounds (Hiyama coupling) has rapidly gained acceptance as a suitable alternative to more commonly used methods such as Stille (Sn), Kumada (Mg), Suzuki (B), and Negishi cross-couplings (Zn).

Organosilanols

Over the past several years, the Pd-catalyzed cross-coupling of silicon compounds (Hiyama coupling) has rapidly gained acceptance as a suitable alternative to more commonly used methods such as Stille (Sn), Kumada (Mg), Suzuki (B), and Negishi cross-couplings (Zn).

Organosilanes for Cross-coupling

Over the past several years, Pd-catalyzed cross-coupling of silicon compounds has rapidly gained acceptance as a suitable alternative to more commonly known methods such as: Stille (Sn), Kumada (Mg), Suzuki (B), and Negishi (Zn) cross-couplings.

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