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About This Item
經驗公式（希爾表示法）:
C9H17BO2
CAS號碼:
分子量：:
168.04
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22
推薦產品
品質等級
化驗
96%
折射率
n20/D 1.433
bp
146 °C
密度
0.922 g/mL at 25 °C
SMILES 字串
CC1(C)OB(OC1(C)C)C2CC2
InChI
1S/C9H17BO2/c1-8(2)9(3,4)12-10(11-8)7-5-6-7/h7H,5-6H2,1-4H3
InChI 密鑰
XGBMQBPLWXTEPM-UHFFFAOYSA-N
應用
Cyclopropylboronic acid pinacol ester can be used:
- As a cyclopropylating reagent in the study of thiophenol S-cyclopropylation, catalyzed by copper(II) acetate.
- In one of the key synthetic steps for the preparation of 5-lipoxygenase activating protein (FLAP) inhibitor.
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Keith R Fandrick et al.
The Journal of organic chemistry, 80(3), 1651-1660 (2015-01-07)
A practical sequence involving a noncryogenic stereospecific boronate rearrangement followed by a robust formylation with an in situ generated DCM anion has been developed for the asymmetric construction of an all-carbon quaternary stereogenic center of a FLAP inhibitor. The key
Emeline Benoit et al.
Beilstein journal of organic chemistry, 15, 1162-1171 (2019-07-12)
The copper-promoted S-cyclopropylation of thiophenols using cyclopropylboronic acid is reported. The procedure operates under simple conditions to afford the corresponding aryl cyclopropyl sulfides in moderate to excellent yields. The reaction tolerates substitution in ortho-, meta- and para-substitution as well as
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